Product Identification

Product Name

2-Chloro-6-(trichloromethyl)pyridine

Synonyms

2,2,2,6-Tetrachloro-2-picoline
2-Chloro-6-trichloromethyl pyridine
Nitrapyrin

CAS

1929-82-4

Formula

C6H3Cl4N

Molecular Weight

230.91

EINECS

217-682-2

RTECS

US7525000

RTECS Class

Agricultural Chemical and Pesticide; Mutagen; Reproductive Effector

Merck

12,6666

Beilstein/Gmelin

1618997

Beilstein Reference

5-20-05-00500

EC Index Number

006-057-00-8

EC Class

Harmful; Dangerous for the Environment

Physical and Chemical Properties

Appearance

Colorless crystals or off-white crystalline solid.

Solubility in water

Insoluble

Melting Point

63 - 64.5

Boiling Point

258

Vapor Pressure

0.023 (25 C)

Density

1.69 g/cm3

Partition Coefficient

2.52

Heat Of Vaporization

47.6 kJ/mol

Heat Of Combustion

-2829 kJ/mol

Usage

Fertilizer additive to control nitrification and prevent loss of soil nitrogen.

First Aid Measures

Ingestion

DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.

Inhalation

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.

Skin

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

Eyes

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Exposure Controls/Personal Protection

Personal Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respirators

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.

Exposure Effects

The toxicological properties of this material have not been investigated.

Exposure limit(s)

NIOSH REL: TWA 10 mg/m3 (total) ST 20 mg/m3 (total) TWA 5 mg/m3 (resp) OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)

Fire Fighting Measures

Flash Point

135

Fire Fighting

Fires involving this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Stability and Reactivity

Stability

No data.

Incompatibilities

Reacts exothermically with acids.