Product Identification

Product Name

Methyl 2-furoate

Synonyms

Methyl 2-furanoate
Methyl furan-2-carboxylate
Methyl pyromucate

CAS

611-13-2

Formula

C6H6O3

Molecular Weight

126.11

EINECS

210-254-6

RTECS

LV1950000

RTECS Class

Drug; Primary Irritant

Merck

13,4328

Beilstein/Gmelin

111110

Beilstein Reference

5-18-06-00103

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

Clear yellow liquid. Pleasant odor.

Solubility in water

Insoluble

Melting Point

36

Boiling Point

181

Vapor Pressure

0.86 (25 C)

Density

1.1739 g/cm3 (15 C)

Partition Coefficient

.99

Heat Of Vaporization

45.22 kJ/mol

Refractive Index

1.4824 (21.4 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Ingestion

The toxicological properties of this substance have not been fully investigated.

Inhalation

The toxicological properties of this substance have not been fully investigated.

Skin

May cause skin irritation. Causes skin irritation.

Eyes

Causes eye irritation. Lachrymator.

EC Risk Phrase

R 36/37/38

EC Safety Phrase

S 26 36

UN (DOT)

2810

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

73

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible Liquid. Extinguishing media: Use water spray to cool fire-exposed containers. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Disposal Code

1

Stability

No data.

Incompatibilities

Strong oxidizing agents

Decomposition

Carbon monoxide, carbon dioxide.

Transport Information

UN Number

2810

HS Code

2932 19 00