Product Identification

Product Name

Titanocene dichloride

Synonyms

bis(Cyclopentadienyl)titanium dichloride
Bis(eta(5)-cyclopentadienyl)titanium dichloride
bis(Pi-Cyclopentadienyl)titanium dichloride
Biscyclopentadienyltitanium(Iv) dichloride
Dichlorobis(Cyclopentadienyl)titanium
Dichlorobis(Eta(5)-Cyclopentadienyl)titanium

CAS

1271-19-8

Formula

C10H10Cl2Ti

Molecular Weight

249

EINECS

215-035-9

RTECS

XR2050000

RTECS Class

Tumorigen; Mutagen; Reproductive Effector

Merck

12,9621

Beilstein/Gmelin

3997 (G)

EC Class

irritant

Physical and Chemical Properties

Appearance

Red to red-orange crystals.

Solubility in water

Insoluble

Melting Point

289 - 291

Density

1.600 g/cm3 (20 C)

Usage

Research chemical.

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

EC Risk Phrase

R 20/22 36/37/38 40

EC Safety Phrase

S 26 36/37/39

UN (DOT)

3282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Disposal Code

24

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, moist air or water.

Decomposition

Hydrogen chloride, carbon monoxide, carbon dioxide, titanium/titanium oxides.

Transport Information

UN Number

3282

HS Code

2931 00 95