Product Identification

Product Name

Glycolic acid phenyl ether

Synonyms

2-(Phenoxy)acetic acid
Glycolic acid phenyl ether
o-Phenylglycolic acid
Phenoxyethanoic acid

CAS

122-59-8

Formula

C8H8O3

Molecular Weight

152.15

EINECS

204-556-7

RTECS

AJ2230000

RTECS Class

Primary Irritant

Merck

12,7407

Beilstein/Gmelin

907949

Beilstein Reference

4-06-00-00634

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

Light tan powder or white solid.

Solubility in water

Very soluble

Melting Point

98 - 100

Boiling Point

285

Vapor Pressure

0.0014 (25 C)

Density

1.36 g/cm3

pKa/pKb

3.17 (pKa)

Partition Coefficient

1.34

Heat Of Vaporization

55.4 kJ/mol

Heat Of Combustion

-3782 kJ/mol

Usage

Used to kill fungus.

Vapor Density

5.25

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use with adequate ventilation.

Hazards Identification

Ingestion

May cause digestive tract disturbances. May be harmful if swallowed.

Inhalation

May cause respiratory tract irritation.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

EC Risk Phrase

R 22 36/37/38

EC Safety Phrase

S 26 36/37/39

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

3

Fire Fighting Measures

Flash Point

115

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

4

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents - strong bases.

Decomposition

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Transport Information

HS Code

2918 90 90