Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity
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Bromadiolone(28772-56-7)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity
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Product Identification

Product Name

Bromadiolone

Synonyms

2H-1-Benzopyran-2-one, 3-[3-(4'-bromo[1,1'-biphenyl]-4-yl)-3-hydroxy-1-phenylpropyl]-4-hydroxy-
3-[3-[4-(4-Bromophenyl)phenyl]-3-hydroxy-1-phenylpropyl]-2-hydroxychromen-4-one
Coumarin, 3-[a-[p-(p-bromophenyl)-b-hydroxyphenethyl]benzyl]-4-hydroxy-
Maki

CAS

28772-56-7

Formula

C30H23BrO4

Molecular Weight

527.41

EINECS

249-205-9

RTECS

GN4934700

RTECS Class

Agricultural Chemical and Pesticide

Merck

12,1403

Beilstein/Gmelin

1335336

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Physical and Chemical Properties

Appearance

Yellowish powder.

Solubility in water

Insoluble

Melting Point

200-210

pKa/pKb

4.50 (pKa)

Usage

Rodenticide (anticoagulant).

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First Aid Measures

Ingestion

Emesis is contraindicated in patients with a prolonged pt and inr due to the risk of bleeding following ipecac-induced increased intracranial pressure. Ipecac may be indicated in the home setting for pediatric patients with an accurate history of recent one-time acute ingestion of these rodenticides. Emesis: use is controversial. May be indicated in the prehospital setting if administered soon (within 30 minutes) after substantial ingestion.

Inhalation

Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.

Skin

Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists. Vitamin k1 (phytonadione) - is a specific antidote and should be administered to any patient with a prolonged pt or inr. Menadione (vitamin k3) should not be used.

Eyes

If symptoms develop, immediately move individual away from exposure and into fresh air. Flush eyes gently with water for at least 15 minutes while holding eyelids apart; seek immediate medical attention.

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Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

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Hazards Identification

Ingestion

Spontaneous emesis may occur.

Inhalation

The compound is toxic by oral exposure.

Skin

Ecchymoses and hematomas occur due to reduced clotting capacity.

Eyes

See inhalation

Hazards

Fire may produce irritating or poisonous gases. Runoff from fire control water may give off poisonous gases. Runoff from fire control or dilution water may cause pollution. When heated to decomposition, it emits toxic fumes of bromine containing compounds.

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Exposure Controls/Personal Protection

Personal Protection

Consult label for cautions specific to product being used & for protective clothing for concentrate > 1%.

Respirators

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.

Poison Class

1

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Fire Fighting Measures

Fire Fighting

(Non-Specific -- Coumarin Derivative Pesticide, Solid, n.o.s.) This material may burn but does not ignite readily. Container may explode in heat of fire. Keep unnecessary people away; isolate hazard area and deny entry. Stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Wear positive pressure breathing apparatus and special protective clothing. Remove and isolate contaminated clothing at the site. If water pollution occurs, notify appropriate authorities.(Non-Specific -- Coumarin Derivative Pesticide, Solid, n.o.s.) Small fires: dry chemicals, carbon dioxide, water spray or foam. Large fires: water spray, fog or foam. Move container from fire area if you can do so without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material.

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Accidental Release Measures

Small spills/leaks

(Non-Specific -- Coumarin Derivative, Pesticide, Solid, n.o.s.) Do not touch spilled material; stop leak if you can do so without risk. Use water spray to reduce vapors. Small spills: absorb with sand or other non-combustible absorbent material and place into containers for later disposal. Small dry spills: with clean shovel place material into clean, dry container and cover; move containers from spill area. Large spills: dike far ahead of spill for later disposal.

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Stability and Reactivity

Stability

No data.