Product Identification

Product Name

5-Amino-m-xylene

Synonyms

3,5-Dimethylaniline
3,5-Dimethylbenzenamine

CAS

108-69-0

Formula

C8H11N

Molecular Weight

121.2

EINECS

203-607-0

RTECS

ZE9625000

RTECS Class

Mutagen

Merck

12,10217

Beilstein/Gmelin

507051

Beilstein Reference

4-12-00-02561

Physical and Chemical Properties

Appearance

Dark brown liquid.

Solubility in water

Slightly soluble

Melting Point

9.8

Boiling Point

220

Density

0.9706 g/cm3 (20 C)

pKa/pKb

9.21 (pKb)

Partition Coefficient

2.21

Usage

Used as a chemical intermediate for the synthesis of pigment red 149.

Odor threshold

0.0240 mg/m3

Refractive Index

1.5581 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid immediately. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Inhalation

May cause severe respiratory tract irritation and possible burns.

Skin

May cause severe skin irritation with possible burns, especially if skin is wet or moist.

Eyes

May cause eye irritation and possible burns.

Ingestion

Harmful if swallowed. Ingestion of nitrate containing compounds can lead to methemoglobinemia. May cause irritation of the digestive tract and possible burns.

Hazards

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.

EC Risk Phrase

R 23/24/25 33 51/53

EC Safety Phrase

S 28 36/37 45 61

UN (DOT)

1711

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Effects may be delayed.

Fire Fighting Measures

Flash Point

93

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible Liquid. To extinguish fire, use water fog, dry chemical, carbon dioxide, or regular foam. Do NOT get water inside containers.

Fire Potential

This chemical is combustible.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition.

Stability and Reactivity

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, acids, acid chlorides, halogens, acid anhydrides, hypochlorite, chloroformates.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1711

Hazard Class

6.1

Packing Group

II