Product Identification

Product Name

Turpentine oil

Synonyms

Gum spirits
Gum thus
Spirits of turpentine
Sulfate turpentine
Wood turpentine

CAS

8006-64-2

Formula

C10H16

Molecular Weight

136

EINECS

232-350-7

RTECS

YO8400000

RTECS Class

Tumorigen; Human Data; Primary Irritant

Beilstein/Gmelin

NA

EC Index Number

650-002-00-6

EC Class

Flammable; Harmful; Irritant; Sensitising; Dangerous for the Environment

Physical and Chemical Properties

Appearance

Colorless liquid. Characteristic odor. Becoming more pronounced and less agreeable on continued exposure

Solubility in water

Insoluble

Melting Point

-50 to -60

Boiling Point

150

Vapor Pressure

6.5 (25 C)

Density

0.854-0.868 g/cm3 (25 C)

Usage

Solvent for oils, resins, varnishes, vehicle for paints.

Vapor Density

4.7

First Aid Measures

Ingestion

Do NOT induce vomiting. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool place in the original container and protect from sunlight. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Wash hands before eating. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation

May cause respiratory tract irritation. Aspiration may cause respiratory swelling and pneumonitis.

Skin

Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.

Eyes

Contact with eyes may cause severe irritation, and possible eye burns.

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 10 20/21/22 36/38 43 51/53 65

EC Safety Phrase

S 36/37 46 61 62

UN (DOT)

1299

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear chemical goggles. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate gloves to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Headache and dizziness may occur with vapor exposure. Seizures may develop after large ingestions. CNS depression including coma may occur following turpentine ingestion. The use of turpentine and water as a vaginal douche has resulted in abortion.

Exposure limit(s)

TLV: 100 ppm; 556 mg/m3 (as TWA) (ACGIH 1992-1993) OSHA PEL: TWA 100 ppm (560 mg/m3) NIOSH REL: TWA 100 ppm (560 mg/m3) NIOSH IDLH: 800 ppm

Poison Class

4

Fire Fighting Measures

Flash Point

35

Autoignition

253

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Can release vapors that form explosive mixtures at temperatures above the flashpoint. To extinguish fire, use water fog, dry chemical, carbon dioxide, or regular foam.

Upper exp. limit

6

Lower exp. limit

.8

Fire Potential

Quite flammable - combustion probable.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Use a spark-proof tool.

Stability and Reactivity

Incompatibilities

Calcium hypochlorite, chlorine, chromic anhydride, chromyl chloride, hexachloromelamine, stannic chloride, and trichloromelamine.

Stability

Stable under normal temperatures and pressures.

Decomposition

Carbon dioxide and carbon monoxide, nitrogen compounds, various hydrocarbons.

Combustion Products

Emits acrid fumes on heating.

Transport Information

UN Number

1299

Hazard Class

3

Packing Group

III