Product Identification

Product Name

Hexylamine

Synonyms

[(3S,8S,9S,10R,13R,14S,17R)-10,13-Dimethyl-17-[(2R)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-yl] chloroformate
1-Aminohexane
3-Cholesteryl chloroformate
Cholest-5-en-3-ol (3b)-, carbonochloridate
Cholesterol carbonochloridat
Cholesterol, chloroformate
Cholesteryloxy)carbonyl chloride

CAS

7144-08-3

CAS

111-26-2

Formula

C28H45ClO2

Formula

C6H15N

Molecular Weight

449.12

Molecular Weight

101.19

EINECS

203-851-8

EINECS

230-447-9

RTECS

MQ4540000

RTECS Class

Primary Irritant

Beilstein/Gmelin

3223154

Beilstein/Gmelin

95286

Beilstein Reference

4-06-00-04010

Beilstein Reference

4-27-00-06641

EC Class

flammable, harmful, corrosive

EC Class

irritant

Physical and Chemical Properties

Appearance

Colorless liquid.

Appearance

White powder.

Solubility in water

Insoluble

Solubility in water

12 g/L

Melting Point

-19

Melting Point

117 - 119

Boiling Point

131

Vapor Pressure

18

Density

0.766 g/cm3 (20 C)

pKa/pKb

10.56(at 25℃) (pKa)

Partition Coefficient

1.42

Vapor Density

3.5

Refractive Index

1.4180 (20 C)

First Aid Measures

Ingestion

Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Discard contaminated clothing in a manner which limits further exposure.

Skin

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.

Eyes

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes

Causes eye burns. Lachrymator. May cause chemical conjunctivitis and corneal damage.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Storage

Keep container closed when not in use. Refrigerator (approx 4 C). Store protected from moisture.

Handling

Use only in a well ventilated area. Minimize dust generation and accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Do not allow contact with water. Discard contaminated shoes. Keep from contact with moist air and steam.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.

Inhalation

May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.

Skin

Causes severe skin irritation. Harmful if absorbed through the skin.

Eyes

Causes severe eye irritation.

Hazards

Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 10 20/21/22 35

EC Risk Phrase

R 34

EC Safety Phrase

S 26 36/37/39 45

UN (DOT)

2733

UN (DOT)

2742

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Effects may be delayed.

Poison Class

4

Fire Fighting Measures

Flash Point

27

Autoignition

270

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out.

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Use agent most appropriate to extinguish fire. Do NOT use straight streams of water.

Upper exp. limit

9.3

Lower exp. limit

2.1

Fire Potential

Flammable/combustible material. May be ignited by heat, sparks or flames.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Do not get water inside containers.

Stability and Reactivity

Disposal Code

5

Incompatibilities

Oxidizing agents, moisture.

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, acids, acid chlorides, acid anhydrides.

Decomposition

Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Decomposition

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Combustion Products

Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2733

UN Number

2742

Hazard Class

3

Hazard Class

6.1

Packing Group

I

Packing Group

I; II; III

HS Code

2915 90 20

HS Code

2921 19 80