Product Identification

Product Name

1-Naphthalene acetic acid

Synonyms

2-(1-Naphthyl)acetic acid
2-Naphthalen-1-ylacetic acid
alpha-Naphthaleneacetic acid.
Appl-Set
Celmone
Transplantone

CAS

86-87-3

Formula

C12H10O2

Molecular Weight

186.21

EINECS

201-705-8

RTECS

QJ0875000

RTECS Class

Agricultural Chemical and Pesticide; Mutagen; Primary Irritant

Merck

12,6458

Beilstein/Gmelin

1308415

Beilstein Reference

4-09-00-02424

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

Odorless, off-white powder.

Solubility in water

0.38 g/L

Melting Point

129 - 131

Boiling Point

352

Vapor Pressure

Negligable.

Density

1.263 g/cm3

pKa/pKb

4.30 (pKa)

Partition Coefficient

2.59

Usage

Herbicide.

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Keep container closed when not in use.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Inhalation

May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema.

Skin

Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.

Eyes

May cause severe eye irritation. May result in corneal injury.

Ingestion

May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.

EC Risk Phrase

R 22 36/37/38

EC Safety Phrase

S 26 36/37/39

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

The toxicological properties of this substance have not been fully investigated.

Poison Class

4

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Disposal Code

4

Incompatibilities

Oxidizing agents.

Stability

Stable under normal temperatures and pressures.

Decomposition

Irritating and toxic fumes and gases.

Transport Information

HS Code

2916 39 00