Product Identification

Product Name

1-(4-nitrophenyl)ethanone

Synonyms

4-Acetylnitrobenzene
Methyl 4-nitrophenyl ketone
p-Nitroacetophenone
p-Nitrophenyl methyl ketone

CAS

100-19-6

Formula

C8H7NO3

Molecular Weight

165.15

EINECS

202-827-4

RTECS

AM9627000

RTECS Class

Mutagen

Beilstein/Gmelin

607777

Beilstein Reference

4-07-00-00657

EC Class

harmful

Physical and Chemical Properties

Appearance

Yellow prisms or bright yellow powder.

Solubility in water

Slightly soluble

Melting Point

76 - 78

Boiling Point

275

Vapor Pressure

0.005 (25 C)

Partition Coefficient

1.54

Heat Of Vaporization

51.4 kJ/mol

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.

Inhalation

Inhalation of dust may cause respiratory tract irritation.

Skin

May cause skin irritation.

Eyes

Dust may cause mechanical irritation.

EC Risk Phrase

R 22

EC Safety Phrase

S 22 36/37

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

4 (Substances and products that must be considered harmful)

Fire Fighting Measures

Flash Point

129

Autoignition

149

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

3

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents - strong bases.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.

Transport Information

UN Number

2811

HS Code

2914 70 90