Product Identification

Product Name

Ruthenium(IV) oxide

Synonyms

Dioxoruthenium
Ruthenium dioxide

CAS

12036-10-1

Formula

O2Ru

Molecular Weight

133.06

EINECS

234-840-6

RTECS

VM2654000

RTECS Class

Other

Beilstein/Gmelin

9364 (G)

Physical and Chemical Properties

Appearance

Gray-black tetragonal crystals

Melting Point

1200

Boiling Point

decomposes

Density

6.97 g/cm3

Usage

Used as a catalyst in various industrial applications or an electrode in electrochemical processes.

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.

Hazards Identification

Inhalation

Inhalation of dust may cause respiratory tract irritation. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.

Skin

Causes skin irritation.

Eyes

Dust may cause mechanical irritation. Causes eye irritation. May cause permanent corneal opacification. May cause chemical conjunctivitis.

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause burns to the gastrointestinal tract.

Hazards

May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.

UN (DOT)

1479

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects

Effects may be delayed.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Extinguishing media: Contact professional fire-fighters immediately. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. Use water spray or carbon dioxide.

Fire Potential

These substances will accelerate burning when involved in a fire.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Incompatibilities

Oxidizing agents, acetone, alcohols, organics, moisture, reducing agents.

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

Decomposition

Irritating and toxic fumes and gases.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1479

Hazard Class

5.1

Packing Group

I; II; III