Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Magnesium phosphide(12057-74-8)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Product Identification

Product Name

Magnesium phosphide

Synonyms

Fumi-Cel
Magtoxin
Trimagnesium diphosphide

CAS

12057-74-8

Formula

Mg3P2

Molecular Weight

134.87

EINECS

235-023-7

RTECS

OM4200000

RTECS Class

Other

Beilstein/Gmelin

169799 (G)

EC Index Number

015-005-00-3

EC Class

Highly flammable; Very toxic; Dangerous for the Environment

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Physical and Chemical Properties

Appearance

Green to yellow crystals

Solubility in water

Reacts

Melting Point

>750

Density

2.055 g/cm3 (25 C)

Usage

Insecticide.

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First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. In case of contact with substance, wipe from skin immediately. Flush with running water for at least 20 minutes.

Eyes

Flush with running water for at least 20 minutes.

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Handling and Storage

Storage

Protect from moist air - will react to produce highly toxic phosphine.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

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Hazards Identification

Inhalation

Highly toxic: contact with water produces toxic gas, may be fatal if inhaled. Inhalation or contact with vapors, substance, or decomposition products may cause severe injury or death.

Skin

See Inhalation.

Eyes

May cause burns.

Hazards

Produce flammable and toxic gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.

UN (DOT)

2011

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Exposure Controls/Personal Protection

Personal Protection

Wear appropriate chemical protective clothing.

Respirators

Wear positive pressure self-contained breathing apparatus.

Exposure Effects

The toxological properties of this substance have not been fully investigated.

Poison Class

1

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Fire Fighting Measures

Fire Fighting

Do not extinguish fire unless flow can be stopped. Do not use water. Use graphite, soda ash, powdered sodium chloride, or suitable dry powder.

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Accidental Release Measures

Small spills/leaks

Do not use water. Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Keep material dry.

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Stability and Reactivity

Stability

No data.

Incompatibilities

React vigorously with most oxidants.

Combustion Products

Fire will produce irritating, corrosive and/or toxic gases.

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Transport Information

UN Number

2011

Hazard Class

4.3

Packing Group

I