Product Identification

Product Name

trans-1,3-Dichloropropene

Synonyms

(E)-1,3-Dichloropropene

CAS

10061-02-6

Formula

C3H4Cl2

Molecular Weight

110.97

RTECS

UC8320000

RTECS Class

Mutagen

Beilstein/Gmelin

1719558

Beilstein Reference

4-01-00-00744

Physical and Chemical Properties

Appearance

A clear colorless liquid with chloroform odor.

Solubility in water

Insoluble

Melting Point

-95

Boiling Point

112

Vapor Pressure

34

Density

1.216 g/cm3 (20 C)

Partition Coefficient

1.41

Usage

Used primarily in soil fumigants for nematodes or as component of soil fumigant mixtures for nematodes.

Vapor Density

1.4

Refractive Index

1.4748 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

Inhalation of vapor may cause respiratory tract irritation. Vapors may cause dizziness or suffocation.

Skin

Causes skin irritation and possible severe skin irritation especially if the skin is wet or moist.

Eyes

Causes eye irritation. Lachrymator.

Hazards

Flash point data for this chemical are not available, however literature indicates that this material is flammable.

UN (DOT)

2047

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure limit(s)

NIOSH: 1ppm TWA: 5 mg/m3 TWA: Potential occupational carcinogen - see Appendix A.

Fire Fighting Measures

Flash Point

27

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire, use water spray, dry chemical, carbon dioxide, or alcohol-resistant foam.

Upper exp. limit

7.8

Lower exp. limit

2.6

Fire Potential

Flammable liquid.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.

Stability and Reactivity

Incompatibilities

Oxidizing agents, aluminum, halogens, metal salts.

Stability

Stable under normal temperatures and pressures.

Decomposition

Hydrogen chloride, carbon monoxide, carbon dioxide.

Combustion Products

Combustion may produce irritants and toxic gases.

Transport Information

UN Number

2047

Hazard Class

3

Packing Group

II; III