Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Vinyl sulfone(77-77-0)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Product Identification

Product Name

Vinyl sulfone

Synonyms

Vinyl sulfone

CAS

77-77-0

Formula

C4H6O2S

Molecular Weight

118.16

EINECS

201-057-6

RTECS

KM7175000

RTECS Class

Drug; Primary Irritant

Beilstein/Gmelin

1071329

Beilstein Reference

4-01-00-02068

EC Class

very toxic, corrosive

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Physical and Chemical Properties

Appearance

Clear colorless liquid.

Solubility in water

Miscible

Melting Point

-26

Boiling Point

234.3

Density

1.1821 g/cm3 (17 C)

Usage

Etherization of cotton by divinyl sulfone and its precursors also forms the basis for a large class of fiber-reactive dyestuffs.

Refractive Index

1.48 (15.5 C)

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First Aid Measures

Ingestion

Do NOT induce vomiting. Allow the victim to rinse his mouth and then to drink 2-4 cupfuls of water, and seek medical advice.

Inhalation

Remove from exposure to fresh air immediately.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

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Handling and Storage

Storage

Refrigerator (approx 4 C).

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

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Hazards Identification

Ingestion

Gastrointestinal irritation with possible fluid shifts could occur.

Inhalation

Inhalation could produce mucous membrane irritation.

Skin

Direct skin contact can produce severe burns.

Eyes

Causes burns.

Hazards

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.

EC Risk Phrase

R 25 27 34

EC Safety Phrase

S 26 36/37/39 45

UN (DOT)

2810

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Exposure Controls/Personal Protection

Personal Protection

If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves.

Respirators

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Poison Class

2

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Fire Fighting Measures

Flash Point

102

Fire Fighting

Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher.

Fire Potential

This chemical is combustible.

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Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

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Stability and Reactivity

Disposal Code

9

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, oxides of sulfur, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

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Transport Information

UN Number

2810

Hazard Class

6.1

Packing Group

I; II; III

HS Code

2930 90 70