Product Identification

Product Name

Copper (II) sulfate

Synonyms

Blue copperas
Blue vicking
Blue vitriol
Bluestone
Calcanthite
Cupric sulfate pentahydrate

CAS

7758-99-8

Formula

CuH10O9S

Molecular Weight

249.68

EINECS

231-847-6

RTECS

GL8900000

RTECS Class

Agricultural Chemical and Pesticide; Tumorigen; Mutagen; Human Data

Merck

13,2682

Beilstein/Gmelin

7192 (G)

EC Index Number

029-004-00-0

EC Class

harmful, irritant, dangerous for the environment

Physical and Chemical Properties

Appearance

Blue crystalline granules or powder. Odorless. White when dehydrated.

Solubility in water

316 g/L (20 C)

Density

2.284 g/cm3 (20 C)

Heat Of Vaporization

Usage

Algaecide, fungicide, insecticide, water treatment, molluscicide, nematicide.

Vapor Density

8.64

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Do not ingest or inhale. Handle under an inert atmosphere. Store protected from air.

Hazards Identification

Inhalation

May cause ulceration and perforation of the nasal septum if inhaled in excessive quantities. Causes respiratory tract irritation with possible burns.

Skin

May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Causes skin irritation and possible burns. May cause itching eczema.

Eyes

Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities. Causes eye irritation and possible burns.

Ingestion

Harmful if swallowed. May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. Ingestion of large amounts of copper salts may cause bloody stools and vomit, low blood pressure, jaundice and coma. Ingestion of copper compounds may produce systemic toxic effects to the kidney and liver and central nervous excitation followed by depression.

Hazards

Containers may explode when heated.

EC Risk Phrase

R 22 36/38 50/53

EC Safety Phrase

S 22 60 61

UN (DOT)

9109

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects

Prolonged or repeated eye contact may cause conjunctivitis. May cause liver and kidney damage. May cause anemia and other blood cell abnormalities. Individuals with Wilson's disease are unable to metabolize copper. Thus, copper accumulates in various tissues and may result in liver, kidney, and brain damage. Laboratory experiments have resulted in mutagenic effects. May cause allergic skin reaction in some individuals. Chronic copper poisoning in man is recognized in the form of Wilson's disease.

Poison Class

3 (Strong toxins)

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Substance is noncombustible. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Extinguishing media: Use extinguishing media most appropriate for the surrounding fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Fire Potential

Nonflammable

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere.

Stability and Reactivity

Incompatibilities

Moisture, air, steel, finely powdered metals, hydroxylamine, magnesium, hydrazine, nitromethane.

Stability

Stable at room temperature in closed containers under normal storage and handling conditions. Air sensitive

Decomposition

Oxides of sulfur, irritating and toxic fumes and gases, oxides of copper, copper fumes.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

9109

Hazard Class

9.2

HS Code

2833 25 00