Product Identification

Product Name

3-(3,5-Dichlorophenyl)-2,4-dioxo-N-isopropylimidazolidine-1-carboxamide

Synonyms

1-Isopropyl carbamoyl-3-(3,5-dichlorophenyl)-Hydantoin
3-(3,5-Dichlorophenyl)hydantoin-1-carboxylic acid isopropylamide
3-(3,5-Dichlorophenyl)-n-(1-methylethyl)2,4-dioxo-1-Imidazolidinecarboxamide
3-(3,5-Dichlorophenyl)-n-Isopropyl-2,4-dioxo-1-Imidazolidinecarboximide
3-(3,5-Dichlorophenyl)-n-isopropyl-2,4-dioxoimidazolidine-1-carboxamide
Glycophene

CAS

36734-19-7

Formula

C13H13Cl2N3O3

Molecular Weight

330.17

EINECS

253-178-9

RTECS

NI8870000

RTECS Class

Agricultural Chemical and Pesticide

Merck

12,5093

Beilstein/Gmelin

895003

Beilstein Reference

5-24-05-00201

EC Index Number

616-054-00-9

EC Class

Carcinogenic Category 3; Dangerous for the Environment

Physical and Chemical Properties

Appearance

Cream to colorless, odorless powder.

Solubility in water

13 mg/L at 20 C

Melting Point

136

Vapor Pressure

4E-9 (25 C)

Density

1.00 g/cm3 (20 C)

Partition Coefficient

3.5

Usage

Fungicide.

First Aid Measures

Ingestion

The possible benefit of early removal of some ingested material by cautious gastric lavage must be weighed against potential complications of bleeding or perforation. Activated charcoal activated charcoal binds most toxic agents and can decrease their systemic absorption if administered soon after ingestion. Activated charcoal: administer charcoal as a slurry (240 ml water/30 g charcoal). Usual dose: 25 to 100 g in adults/adolescents.

Inhalation

Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. Administer oxygen and assist ventilation as required. Treat bronchospasm with beta2 agonist and corticosteroid aerosols.

Skin

Remove contaminated clothing. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse.

Eyes

Irrigate exposed eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, lacrimation, or photophobia persist, the patient should be seen in a health care facility.

Handling and Storage

Storage

Store in a cool, dry location, away from food/feed, fertilizers or seed.

Handling

Avoid contact. Adequately decomtaminate all tools and equipment after use. Use protective equipment.

Hazards Identification

Ingestion

Toxic by ingestion.

Inhalation

Harmful if inhaled. Acute or chronic exposure can caush asthmatic reaction or other pulmanary problems.

Skin

Irritation. Absorption may be harmful.

Eyes

Causes irritation.

Exposure Controls/Personal Protection

Personal Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respirators

NIOSH/MSHA approved air respirator for pesticide dust when handling spills or leaks or when airborne concentrations exceed recommended limits.

Poison Class

4

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use agent most appropriate to extinguish fire.

Accidental Release Measures

Small spills/leaks

Shovel/scoop loose material and place in an appropriate container. Avoid dust generation. Stay up wind. Clean residue from exposed surfaces. Use appropriate protective equipment.

Stability and Reactivity

Stability

Stable at normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents.

Decomposition

Oxides of carbon, nitrogen and sulfur. Ammonia.