Product Identification

Product Name

Bismuth nitrate oxide

Synonyms

(Nitrooxy)oxobismuthine
Bismuth nitrate oxide
Bismuth(III) nitrate basic
Bismuthyl nitrate
Oxobismuthanyl nitrate

CAS

10361-46-3

Formula

BiNO4

Molecular Weight

286.98

EINECS

233-792-3

Beilstein/Gmelin

47199 (G)

Physical and Chemical Properties

Appearance

White powder

Solubility in water

Insoluble

Density

4.93 g/cm3 (25 C)

First Aid Measures

Ingestion

If swallowed, wash out mouth with water provided person is conscious. Call a physician.

Inhalation

If inhaled, remove to fresh air. If breathing becomes difficult, call a physician.

Skin

In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.

Eyes

In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.

Handling and Storage

Storage

Keep tightly closed. Keep away from combustible materials, heat, sparks, and open flame. Store in a cool dry place. Store in the dark.

Hazards Identification

Inhalation

Harmful if inhaled. Material is irritating to mucous membranes and upper respiratory tract.

Skin

Causes skin irritation. Harmful if absorbed through skin.

Eyes

Causes eye irritation.

Ingestion

Harmful if swallowed.

Hazards

Emits toxic fumes under fire conditions. Contact with other material may cause fire. May accelerate combustion.

EC Risk Phrase

8 36/37/38

EC Safety Phrase

17 26 36/37/39

UN (DOT)

1477

Exposure Controls/Personal Protection

Personal Protection

Compatible chemical-resistant gloves. Chemical safety goggles.

Respirators

Government approved respirator.

Exposure Effects

Oxidizing. Irritant. Contact with combustible material may cause fire. Irritating to eyes, respiratory system and skin. Target organ(s): Blood. Kidneys.

Poison Class

3

Fire Fighting Measures

Fire Fighting

Extinguish using Carbon dioxide, dry chemical powder, or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Fire Potential

These substances will accelerate burning when involved in a fire.

Accidental Release Measures

Small spills/leaks

Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.

Stability and Reactivity

Stability

Stable at normal temperatures and pressures. Sensitive to light.

Incompatibilities

Strong oxidizing agents, Strong acids, Organic materials, Finely powdered metals Alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannin, salicylic acid, and sulfur.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1477

Hazard Class

5.1

Packing Group

II