Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Potassium superoxide(12030-88-5)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Product Identification

Product Name

Potassium superoxide

Synonyms

Potassium dioxide

CAS

12030-88-5

Formula

KO2

Molecular Weight

71.099999999999994

EINECS

234-746-5

RTECS

TT6053000

RTECS Class

Mutagen

Beilstein/Gmelin

10084 (G)

EC Class

oxidizing, corrosive

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Physical and Chemical Properties

Appearance

A yellowish to white solid.

Solubility in water

Rigorous decomposition

Melting Point

560

Density

2.14 g/cm3

Usage

Used in chemical oxygen generators. Canister rebreathers for fire fighting/mine rescue.

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First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush skin or eyes with running water for at least 20 minutes.

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Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation.

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Hazards Identification

Ingestion

May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.

Inhalation

May cause severe respiratory tract irritation and possible burns.

Skin

May cause severe skin irritation and burns.

Eyes

Contact with eyes may cause severe irritation, and possible eye burns.

Hazards

May explode from friction, heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard.

EC Risk Phrase

R 8 35

EC Safety Phrase

S 17 26 36/37/39 45

UN (DOT)

2466

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Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

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Fire Fighting Measures

Fire Fighting

Use dry chemical, graphite, or dry earth. Use water only if flooding quantities are available. Apply water from as far a distance as possible.

Fire Potential

May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire.

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Accidental Release Measures

Small spills/leaks

Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Use water spray to disperse the gas/vapor.

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Stability and Reactivity

Disposal Code

22

Incompatibilities

Oxidizing agents, carbon, 2-aminophenol + tetrahydrofuran, acids, alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g. benzene, chrysene

Stability

Stable under normal temperatures and pressures.

Decomposition

Irritating and toxic fumes and gases.

Combustion Products

Fire may produce irritating and/or toxic gases.

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Transport Information

UN Number

2466

Hazard Class

5.1

Packing Group

I

HS Code

2825 90 80