Product Identification

Product Name

2-Nitrobenzaldehyde

Synonyms

o-Nitrobenzaldehyde

CAS

552-89-6

Formula

C7H5NO3

Molecular Weight

151.12

EINECS

209-025-3

RTECS

CU7300000

RTECS Class

Mutagen

Merck

12,6684

Beilstein/Gmelin

742624

Beilstein Reference

4-07-00-00584

Physical and Chemical Properties

Appearance

Light yellow powder.

Solubility in water

Slightly soluble.

Melting Point

41 - 43

Boiling Point

285

Vapor Pressure

0.003 (25 C)

Density

1.35 g/cm3 (25 C)

Partition Coefficient

1.74

Heat Of Vaporization

52.4 kJ/mol

Vapor Density

5.2

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep container closed when not in use. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid prolonged or repeated contact with skin. Avoid contact with skin and eyes. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Causes gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

Causes respiratory tract irritation. Irritation may lead to chemical pneumonitis and pulmonary edema.

Skin

Causes skin irritation.

Eyes

Causes eye irritation. May cause eye injury.

EC Risk Phrase

R 20/22 36/37/38

EC Safety Phrase

S 26 36/37/39

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Poison Class

3 (Strong toxins)

Fire Fighting Measures

Flash Point

144

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

3

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

Incompatibilities

Strong oxidizing agents.

Decomposition

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information

HS Code

2913 00 00