Product Identification

Product Name

2-Amino-3-nitrotoluene

Synonyms

1-Amino-2-methyl-6-nitrobenzene
2-Amino-3-nitrotoluene
2-Nitro-6-methylaniline
3-Nitro-2-aminotoluene
6-Nitro-o-toluidine
Benzenamine, 2-methyl-6-nitro-

CAS

570-24-1

Formula

C7H8N2O2

Molecular Weight

152.15

EINECS

209-329-6

RTECS

XU8225000

Beilstein/Gmelin

1868029

Beilstein Reference

4-12-00-01807

EC Index Number

612-025-00-X

EC Class

toxic, dangerous for the environment

Physical and Chemical Properties

Appearance

Orange-yellow prisms or brown granular powder.

Solubility in water

Insoluble

Melting Point

92 - 94

Boiling Point

120 - 124 (1 torr)

Density

1.19 g/cm3 (100 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Causes digestive tract irritation.

Inhalation

May cause irritation of the mucous membranes.

Skin

Causes skin irritation. Absorption into the body may cause cyanosis.

Eyes

Causes eye irritation. May cause eye burns.

Hazards

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.

EC Risk Phrase

R 23/24/25 33 51/53

EC Safety Phrase

S 28 36/37 45 61

UN (DOT)

2660

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

110

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Combustible material; may burn but does not ignite readily. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Fire Potential

Combustible material: may burn but does not ignite readily.

Accidental Release Measures

Small spills/leaks

Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition.

Stability and Reactivity

Disposal Code

9

Incompatibilities

Acids - acid chlorides - acid anhydrides - chloroformates - strong oxidizing agents.

Stability

Stable under normal temperatures and pressures.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2660

Hazard Class

6.1

Packing Group

III

HS Code

2921 43 00