Product Identification

Product Name

1-Hexanol

Synonyms

Amyl carbinol
Caproyl alcohol
Hexan-1-ol
n-Hexanol
n-Hexyl alcohol
Pentylcarbinol

CAS

111-27-3

Formula

C6H14O

Molecular Weight

102.18

EINECS

203-852-3

RTECS

MQ4025000

RTECS Class

Primary Irritant

Merck

13,4715

Beilstein/Gmelin

969167

Beilstein Reference

4-01-00-01694

EC Index Number

603-059-00-6

EC Class

Harmful

Physical and Chemical Properties

Appearance

Clear, colorless liquid with a fruity odor.

Solubility in water

5.9 g/L (20 C)

Melting Point

-45

Boiling Point

156

Vapor Pressure

0.5 (21 C)

Density

0.8322 g/cm3

Partition Coefficient

2.03

Heat Of Vaporization

32.09 kJ/mol

Heat Of Combustion

-3980 kJ/mol

Usage

Solvent, laboratory reagent.

Vapor Density

4.5

Saturation Concentration

1200 ppm (0.12%) at 25 C (calculated)

Odor threshold

0.01 ppm

Refractive Index

1.4162 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation

Inhalation of high concentrations may cause central nervous system effects characterized by headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation.

Skin

May cause skin irritation and dermatitis.

Eyes

Causes eye irritation with redness and tearing. Splashes have caused temporary corneal damage.

Ingestion

Harmful if swallowed. May cause headache, nausea, drowsiness and dizziness. Aspiration into the lungs may occur during swallowing or vomiting, resulting in lung damage.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 22

EC Safety Phrase

S 24/25

UN (DOT)

2282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Prolonged skin contact may result in drying and cracking of the skin.

Poison Class

4

Fire Fighting Measures

Flash Point

62

Autoignition

285

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool. Combustible Liquid. To extinguish fire, use dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.

Upper exp. limit

8

Lower exp. limit

1.2

Fire Potential

Moderate fire hazard, when exposed to heat or flame; can react with oxidizing materials.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Scoop up with a nonsparking tool, then place into a suitable container for disposal. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code

1

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizers, inorganic acids, and halogens.

Decomposition

Carbon dioxide and carbon monoxide may form when heated to decomposition.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2282

Hazard Class

3

Packing Group

III

HS Code

2905 19 00