Product Identification

Product Name

1-Chloro-3-nitrobenzene

Synonyms

m-Chloronitrobenzene
m-Nitrochlorobenzene

CAS

121-73-3

Formula

C6H4ClNO2

Molecular Weight

157.56

EINECS

204-496-1

RTECS

CZ0940000

RTECS Class

Tumorigen

Merck

13,2170

Beilstein/Gmelin

1907947

Beilstein Reference

4-05-00-00722

EC Class

toxic

Physical and Chemical Properties

Appearance

Pale yellow crystals.

Solubility in water

Insoluble

Melting Point

46

Boiling Point

236

Vapor Pressure

0.15 (25 C)

Density

1.343 g/cm3 (20 C)

Partition Coefficient

2.41

Heat Of Vaporization

55.8 kJ/mol

Heat Of Combustion

-2820 kJ/mol

Usage

Chemical intermediate for meta-chloroaniline(dye & herbicide chemical int).

Refractive Index

1.5374 (80 C)

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with skin and eyes. Do not ingest or inhale.

Hazards Identification

Inhalation

May cause effects similar to those described for ingestion.

Skin

Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.

Eyes

Causes eye irritation.

Ingestion

Harmful if swallowed. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May cause central nervous system depression. May cause cyanosis, characterized by bluish skin.

Hazards

Containers may explode when heated.

EC Risk Phrase

R 22 23/24 33 51/53

EC Safety Phrase

S 28 36/37 45 61

UN (DOT)

1578

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

May cause liver and kidney damage. May cause anemia and other blood cell abnormalities. May cause fatigue, dizziness, headache, insomnia and weight loss.

Poison Class

3

Fire Fighting Measures

Flash Point

103

Autoignition

>450

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use agent most appropriate to extinguish fire.

Upper exp. limit

8.8

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.

Stability and Reactivity

Disposal Code

9

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, ammonia.

Decomposition

Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1578

Hazard Class

6.1

Packing Group

II

HS Code

2904 90 85