Product Identification

Product Name

4-Bromobenzylamine

Synonyms

(4-Bromophenyl)methanamine
4-Bromobenzyl amine
p-Bromobenzenemethanamine
p-Bromobenzylamine

CAS

3959-07-7

Formula

C7H8BrN

Molecular Weight

186.05

EINECS

223-559-4

Physical and Chemical Properties

Appearance

White to almost white solid.

Solubility in water

Very soluble

Melting Point

20

Boiling Point

250

Vapor Pressure

0.024 (25 C)

Density

1.481 g/cm3 (20 C)

pKa/pKb

4.88 (pKb)

Partition Coefficient

1.68

Heat Of Vaporization

48.6 kJ/mol

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.

Eyes

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation with water is required (at least 30 minutes).

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container. Corrosives area.

Hazards Identification

Ingestion

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May cause perforation of the digestive tract. May cause systemic effects.

Inhalation

Causes chemical burns to the respiratory tract. Aspiration may lead to pulmonary edema. May cause systemic effects.

Skin

Causes skin burns. May cause skin rash (in milder cases), and cold and clammy skin with cyanosis or pale color.

Eyes

Causes eye burns. May cause chemical conjunctivitis and corneal damage.

EC Risk Phrase

R: 34

EC Safety Phrase

S: 26 36/37/39 45

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

104

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Incompatibilities

Oxidizing agents.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.

Combustion Products

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.