Product Identification

Product Name

1,2,3-Tribromopropane

Synonyms

Glycerol tribromohydrin
s-Tribromopropane
sym-Tribromopropane

CAS

96-11-7

Formula

C3H5Br3

Molecular Weight

280.77999999999997

EINECS

202-478-8

RTECS

TZ8300000

RTECS Class

Mutagen; Reproductive Effector

Merck

12,9745

Beilstein/Gmelin

1732082

Beilstein Reference

4-01-00-00221

Physical and Chemical Properties

Appearance

Liquid.

Solubility in water

Insoluble

Melting Point

16

Boiling Point

222

Vapor Pressure

0.18 (25 C)

Density

2.43 g/cm3 (0 C)

Partition Coefficient

2.81

Heat Of Vaporization

43.8 kJ/mol

Usage

Nematocide.

Refractive Index

1.5819 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Use only in a chemical fume hood.

Hazards Identification

Ingestion

The toxicological properties of this substance have not been fully investigated.

Inhalation

Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

EC Risk Phrase

R 20/21/22 36/38 40

EC Safety Phrase

S 26 36/37/39

UN (DOT)

2810

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

87

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Combustible Liquid. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide, hydrogen bromide.

Transport Information

UN Number

2810