Product Identification

Product Name

1,2-Epoxy-3-(tolyloxy)propane

Synonyms

Cresol glycidal ether
Cresol glycidyl ether
Methylphenyl glycidyl ether
Oxirane, [(methylphenoxy)methyl]-
Propane, 1,2-epoxy-3-(tolyloxy)-
Tolyl glycidyl ether

CAS

26447-14-3

Formula

C10H12O2

Molecular Weight

164.22

EINECS

247-711-4

RTECS

TZ3699000

RTECS Class

Mutagen

Beilstein/Gmelin

NA

EC Index Number

603-056-00-X

EC Class

Mutagenic Category 3; Irritant; Sensitising; Dangerous for the Environment

Physical and Chemical Properties

Appearance

Colorless liquid.

Boiling Point

259

Density

1.09 g/cm3 (20 C)

Heat Of Vaporization

Heat Of Combustion

-6232 kJ/mol

First Aid Measures

Ingestion

DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician.

Inhalation

IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used.

Skin

IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.

Eyes

First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Inhalation

Fumes from cured epoxy resins may result in coughing, and bronchospasm persisting for several days.

Skin

Allergic contact dermatitis occurs in a significant number of occupational exposures. Exposures may result in severe burns to the skin. Eczema, urticaria and photodermatitis have been reported following dermal exposures.

Ingestion

Ingestion of polyamines may result in burns to the oral pharynx and esophagus. Dysphagia and drooling may be noted.

Hazards

Wear full body and respiratory protection.

Exposure Controls/Personal Protection

Personal Protection

Chemical splash goggles in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. Whre chemical resistant gloves. To prevent repeated or prolonged skin contact, wear impervious clothing and boots.

Respirators

Use NIOSH/MSHA approved respirator appropriate for exposure of concern.

Exposure Effects

Epichlorohydrin ingestion has resulted in cyanosis, muscular relaxation or paralysis, tremor, seizures, and respiratory arrest in animal studies.

Fire Fighting Measures

Flash Point

93

Fire Fighting

Fire Extinguishing Agents Not to Be Used: Water may be ineffective.Fire Extinguishing Agents: Dry chemical, foam, carbon dioxide

Accidental Release Measures

Small spills/leaks

If you spill this chemical, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with alcohol followed by washing with a strong soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Stability and Reactivity

Stability

No data.

Incompatibilities

Reacts as weak organic acids Incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides React with acids, bases, and oxidizing and reducing agents.

Combustion Products

Wear full body and respiratory protection.