Product Identification

Product Name

1-Hexen-3-ol

Synonyms

1-Propylallyl alcohol
1-Vinylbutanol
3-Hydroxy-1-hexene
Propylvinylcarbinol

CAS

4798-44-1

Formula

C6H12O

Molecular Weight

100.16

EINECS

225-355-0

Beilstein/Gmelin

1720166

Beilstein Reference

3-01-00-01924

Physical and Chemical Properties

Appearance

White crystals

Solubility in water

Slightly soluble

Melting Point

-72

Boiling Point

134-135

Density

0.884 g/cm3 (20 C)

Partition Coefficient

1.64

Refractive Index

1.4297 (18 C)

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

Handling

Use spark-proof tools and explosion proof equipment. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion

The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.

Inhalation

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

Hazards

Vapors can travel to a source of ignition and flash back.

EC Risk Phrase

R 10 22

EC Safety Phrase

S 23 36/37

UN (DOT)

1987

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

4

Fire Fighting Measures

Flash Point

35

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing media: Use carbon dioxide or dry chemical.

Fire Potential

Flammable Liquid.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Remove all sources of ignition. Use a spark-proof tool.

Stability and Reactivity

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, strong acids.

Decomposition

Carbon monoxide, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1987

Hazard Class

3

Packing Group

I; II; III