Product Identification

Product Name

3-Hydroxy-4-methoxyaniline

Synonyms

3-Hydroxy-4-methoxyaniline
5-Amino-2-methoxyphenol

CAS

1687-53-2

Formula

C7H9NO2

Molecular Weight

139.16

EINECS

216-873-8

Beilstein/Gmelin

2717084

Beilstein Reference

4-13-00-02507

Physical and Chemical Properties

Appearance

Grey - brown solid.

Solubility in water

Insoluble

Melting Point

128 - 131

Boiling Point

277

Density

1 g/cm3

Partition Coefficient

.72

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Ingestion

Harmful if swallowed.

Inhalation

Harmful if inhaled. Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

EC Risk Phrase

R 20/22 36/37/38

EC Safety Phrase

S 26 36/37/39

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code

3

Stability

No data.

Incompatibilities

Strong oxidizing agents, strong bases.

Decomposition

Carbon monoxide, oxides of nitrogen, carbon dioxide.

Transport Information

UN Number

2811

HS Code

2922 50 00