Product Identification

Product Name

Platinum(II) chloride

Synonyms

Muriate of platinum
Platinum chloride
Platinum dichloride
Platinum(II) chloride

CAS

10025-65-7

Formula

Cl2Pt

Molecular Weight

266

EINECS

233-034-1

RTECS

TP2275000

RTECS Class

Mutagen; Primary Irritant

Merck

12,7687

Beilstein/Gmelin

9308 (G)

EC Class

irritant, sensitizing

Physical and Chemical Properties

Appearance

Grayish-green to brown powder.

Solubility in water

Insoluble

Melting Point

581

Density

6.05 g/cm3

Usage

In synthesis of platinum salts.

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Inhalation

Causes respiratory tract irritation. May cause asthmatic attacks due to allergic sensitization of the respiratory tract. Causes irritation of mucous membrane. Inhalation may produce lachrimation, sneezing, rhinnorhea, cough, dyspnea, bronchial asthma, and cyanosis.

Skin

Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with the skin may cause urticaria (hives).

Eyes

Causes eye irritation. In the eyes, the dusts cause a burning sensation, lachrimation, and conjunctival hyperemia, sometimes associated with photophobia.

Ingestion

May cause irritation of the digestive tract.

Hazards

Contact with metals may evolve flammable hydrogen gas.

EC Risk Phrase

R 36/38 42/43

EC Safety Phrase

S 22 24 37 45

UN (DOT)

3260

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause effects similar to those of acute inhalation.

Exposure limit(s)

IDHL: 4 mg/m3

Poison Class

2

Fire Fighting Measures

Flash Point

580

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Extinguishing media: Use agent most appropriate to extinguish fire.

Fire Potential

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks

Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions.

Stability and Reactivity

Disposal Code

27

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents

Decomposition

Hydrogen chloride.

Combustion Products

Toxic gases and vapors (such as chlorine) may be released when chlorine-containing soluble platinum salts decompose.

Transport Information

UN Number

3260

Hazard Class

8

Packing Group

I; II; III

HS Code

2843 90 90