Product Identification

Product Name

N-Methylformanilide

Synonyms

N-Formyl-N-methylaniline
N-Methyl-N-formylaniline
N-Methyl-N-phenylformamide
N-Phenyl-N-methylformamide

CAS

93-61-8

Formula

C8H9NO

Molecular Weight

135.16999999999999

EINECS

202-262-3

Beilstein/Gmelin

636496

Beilstein Reference

4-12-00-00370

EC Class

irritant

Physical and Chemical Properties

Appearance

Clear, colorless liquid.

Solubility in water

Slightly soluble

Melting Point

8 - 13

Boiling Point

243

Vapor Pressure

2.66 Pa (25 C)

Density

1.107 g/cm3 (0 C)

Refractive Index

1.5625 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Ingestion may cause mild irritation of the mouth.

Inhalation

Causes respiratory tract irritation. Vapor or mist is irritating to the mucous membranes and upper respiratory tract.

Skin

Causes skin irritation.

Eyes

Causes eye irritation. Vapors may cause eye irritation.

EC Risk Phrase

R 36/37/38

EC Safety Phrase

S 26 36

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

126

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Flush spill area with water. Provide ventilation.

Stability and Reactivity

Disposal Code

1

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.

Transport Information

HS Code

2924 29 95