Product Identification

Product Name

Ditetradecyl peroxydicarbonate

Synonyms

Ditetradecyl peroxydicarbonate
Perkadox 26
Peroxydicarbonic acid, C,C'-ditetradecyl ester
Peroxydicarbonic acid, ditetradecyl ester

CAS

53220-22-7

Formula

C30H58O6

Molecular Weight

514.79

EINECS

258-436-4

Beilstein/Gmelin

NA

Physical and Chemical Properties

Appearance

Must be stored with stringent temperature control measures.

Solubility in water

3.9E-8 G/L

Boiling Point

547

Vapor Pressure

5.3E-12 (25 C)

Density

0.947 g/cm3 (25 C)

Partition Coefficient

14.69 (25 C)

Heat Of Vaporization

82.58 kJ/mol

First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes.

Eyes

Immediately flush with running water for at least 20 minutes.

Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion

See Inhalation.

Inhalation

May cause severe injury or burns.

Skin

See Inhalation.

Eyes

See Inhalation.

Hazards

Sensitive to temperature rises. Above a given Control Temperature they decompose violently and catch fire. May ignite combustibles (wood, paper, oil, clothing, etc.). May ignite spontaneously if exposed to air. May be ignited by heat, sparks or flames. May burn rapidly with flare-burning effect. Containers may explode when heated. Runoff may create fire or explosion hazard.

UN (DOT)

2595; 2892

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Flash Point

222

Fire Fighting

The temperature of the substance must be maintained at or below the Control Temperature at all times. SMALL FIRES: Water spray or fog is preferred; if water not available use dry chemical, carbon dioxide or regular foam. LARGE FIRES: Flood fire area with water from a distance. Use water spray or fog; do not use straight streams. Move containers from fire area if you can do it without risk. Do not move cargo or vehicle if cargo has been exposed to heat. Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. BEWARE OF POSSIBLE CONTAINER EXPLOSION. ALWAYS stay away from tanks engulfed in fire. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Fire Potential

May explode from heat, contamination or loss of temperature control. Particularly sensitive to temperature rises.

Accidental Release Measures

Small spills/leaks

ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Do not touch or walk through spilled material. Stop leak if you can do it without risk. SMALL SPILLS: Take up with inert, damp, noncombustible material using clean non-sparking tools and place into loosely covered plastic containers for later disposal.

Stability and Reactivity

Stability

No data.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2595; 2892

Hazard Class

5.2