Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Zinc peroxide (1314-22-3)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Product Identification

Product Name

Zinc peroxide

Synonyms

Zinc dioxide
Zinc superoxide

CAS

1314-22-3

Formula

O2Zn

Molecular Weight

97.37

EINECS

215-226-7

RTECS

ZH4865000

Merck

12,10282

Beilstein/Gmelin

107267 (G)

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Physical and Chemical Properties

Appearance

A white powder.

Solubility in water

Decomposes

Melting Point

212

Density

1.57 g/cm3 (20 C)

Usage

In pharmaceuticals, accelerator in rubber compounding, curing agent for synthetic elastomers.

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First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Aspirated zinc stearate may cause severe respiratory irritation.

Skin

Remove contaminated clothing and wash exposed area thoroughly with soap and water. A physician should examine the area if irritation or pain persists.

Eyes

Immediately flush skin or eyes with running water for at least 20 minutes.

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Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

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Hazards Identification

Ingestion

Serious gi complications have resulted from the ingestion of concentrated solutions and enemas with dilute peroxide solutions.

Inhalation

Inhalation of vapors from concentrated (greater than 10%) solutions may result in severe pulmonary irritation. Interstitial lung disease and respiratory arrest have also been reported following massive exposures.

Skin

Dermal exposure to dilute (3%) solutions generally results in a bleaching of the affected area in association with a tingling sensation and lasts 2 to 3 hours, if washed promptly after contact.

Eyes

See Inhalation.

Hazards

May explode from friction, heat or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). Some will react explosively with hydrocarbons (fuels). Containers may explode when heated. Runoff may create fire or explosion hazard.

UN (DOT)

1516

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Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Poison Class

3

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Fire Fighting Measures

Fire Fighting

Flood with water. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible.

Fire Potential

May explode from friction, heat or contamination. These substances will accelerate burning when involved in a fire.

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Accidental Release Measures

Small spills/leaks

Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers.

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Stability and Reactivity

Incompatibilities

Mixtures with combustible material can sometimes be ignited by friction or contact with moisture Mixtures with aluminum or zinc powder burn brilliantly.

Stability

No data.

Combustion Products

Fire may produce irritating and/or toxic gases.

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Transport Information

UN Number

1516

Hazard Class

5.1

Packing Group

II