Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Methallyl alcohol(513-42-8)

Product Identification Physical and Chemical Properties First Aid Measures Handling and Storage Hazards Identification Exposure Controls/Personal Protection Fire Fighting Measures Accidental Release Measures Stability and Reactivity Transport Information
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Product Identification

Product Name

Methallyl alcohol

Synonyms

2-Methyl-2-propen-1-ol
2-Methylprop-2-en-1-ol
Isopropenyl carbinol
Methyl allyl alcohol

CAS

513-42-8

Formula

C4H8O

Molecular Weight

72.12

EINECS

208-161-0

RTECS

UD5250000

RTECS Class

Primary Irritant

Beilstein/Gmelin

969226

Beilstein Reference

4-01-00-02114

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Physical and Chemical Properties

Appearance

Colorless liquid with a pungent odor.

Solubility in water

Slightly soluble

Melting Point

-50

Boiling Point

114

Vapor Pressure

7

Density

0.8677 g/cm3 (0 C)

Partition Coefficient

.6

Usage

Used in the chemical process industry.

Refractive Index

1.4229 (20 C)

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First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Remove to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Remove contaminated clothing and shoes. Flush with water.

Eyes

Flush with water for at least 15 min., lifting lids occasionally.

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Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Handling

Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

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Hazards Identification

Inhalation

Vapors may cause dizziness or suffocation. May cause irritation or burns.

Skin

May cause irritation or burns.

Eyes

See Skin.

Ingestion

Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. May polymerize explosively when heated or involved in a fire. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

UN (DOT)

2614

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Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Exposure Effects

The toxological properties of this substance have not been fully investigated.

Poison Class

2

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Fire Fighting Measures

Flash Point

33

Autoignition

320

Fire Fighting

Fire Extinguishing Agents Not to Be Used: Water.Fire Extinguishing Agents: Dry chemical, alcohol foam, or carbon dioxide.

Fire Potential

HIGHLY FLAMMABLE.

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Accidental Release Measures

Small spills/leaks

Keep sparks, flames, and other sources of ignition away. Keep material out of water sources and sewers. Build dikes to contain flow as necessary. Use water spray to knock-down vapors.

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Stability and Reactivity

Incompatibilities

May react vigorously with strong oxidizing agents May react exothermically with reducing agents to release hydrogen gas.

Stability

Stable under normal temperatures and pressures.

Decomposition

Carbon monoxide, carbon dioxide.

Combustion Products

Irritating vapors and toxic gases, such as carbon dioxide and carbon monoxide, may be formed when involved in fire.

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Transport Information

UN Number

2614

Hazard Class

3

Packing Group

III