Product Identification

Product Name

Lithium chloride

CAS

7447-41-8

Formula

ClLi

Formula

LiCl

Molecular Weight

42.39

EINECS

231-212-3

RTECS

OJ5950000

RTECS Class

Tumorigen; Drug; Mutagen; Reproductive Effector; Human Data; Primary Irritant

Merck

13,5550

Beilstein/Gmelin

13672 (G)

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

White crystals, granules or crystalline powder, deliquescent.

Solubility in water

769 g/L

Melting Point

614

Boiling Point

1382

Vapor Pressure

360 (1235 C)

Density

2.07 g/cm3

Heat Of Vaporization

Usage

Manufacture mineral waters, in pyrotechnics, soldering aluminum, in refrigerating machines.

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get on skin or in eyes. Do not ingest or inhale. Discard contaminated shoes.

Hazards Identification

Inhalation

May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.

Skin

May cause severe irritation and possible burns. Chronic ingestion may cause dizziness, ringing in the ears, visual disturbances, tremors, and mental confusion. Prolonged absorption may affect electrolyte balance and impair kidney function. Dehydration, weight loss, skin effects, and thyroid disturbances have been reported.

Eyes

Contact with eyes may cause severe irritation, and possible eye burns.

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause muscle tremor and impaired motor function. May cause circulatory system failure. May cause cardiac disturbances. May cause tremors and convulsions. May cause central nervous system effects.

EC Risk Phrase

R 22 36/37/38

EC Safety Phrase

S 26 36/37/39

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects

Chronic ingestion may cause dizziness, ringing in the ears, visual disturbances, tremors, and mental confusion. Prolonged absorption may affect electrolyte balance and impair kidney function. Dehydration, weight loss, skin effects, and thyroid disturbances have been reported.

Poison Class

3

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use extinguishing media appropriate to the surrounding fire. Substance is noncombustible. Extinguishing media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

14

Incompatibilities

Bromine trifluoride, strong acids.

Stability

Stable under normal temperatures and pressures.

Decomposition

Hydrogen chloride, chlorine, irritating and toxic fumes and gases.

Transport Information

HS Code

2827 39 80