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Imidazo[1,2-a]pyridine, 6-fluoro- (9CI)

Product Name
Imidazo[1,2-a]pyridine, 6-fluoro- (9CI)
CAS No.
139022-27-8
Chemical Name
Imidazo[1,2-a]pyridine, 6-fluoro- (9CI)
Synonyms
6-fluoroimidazo[1,2-a]pyridine;6-FluoroiMidazole[1,2-a]pyridine;6-Fluoroimidazolo[1,2-a]pyridine;Imidazo[1,2-a]pyridine, 6-fluoro-;Imidazo[1,2-a]pyridine, 6-fluoro- (9CI)
CBNumber
CB01059285
Molecular Formula
C7H5FN2
Formula Weight
136.13
MOL File
139022-27-8.mol
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Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) Property

Melting point:
70-71°
storage temp. 
Sealed in dry,Room Temperature
form 
solid
color 
Brown
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Safety

HazardClass 
IRRITANT
HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H320Causes eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
F591948
Product name
6-Fluoroimidazo[1,2-a]pyridine
Packaging
250mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
V2885
Product name
6-Fluoroimidazo[1,2-a]pyridine
Packaging
250mg
Price
$116
Updated
2021/12/16
Matrix Scientific
Product number
048230
Product name
6-Fluoroimidazo[1,2-a]pyridine
Purity
>95%
Packaging
1g
Price
$128
Updated
2021/12/16
Apolloscientific
Product number
PC200221
Product name
6-Fluoroimidazo[1,2-a]pyridine
Packaging
1g
Price
$138
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-3-Q8
Product name
6-Fluoroimidazo[1,2-a]pyridine
Packaging
1g
Price
$285
Updated
2021/12/16
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Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) Chemical Properties,Usage,Production

Synthesis

107-20-0

21717-96-4

139022-27-8

To a solution of 2-amino-5-fluoropyridine (10 g) in ethanol (200 mL) was slowly added 50% aqueous chloroacetaldehyde (56 mL, 4.0 equiv). The reaction mixture was heated under reflux conditions for 2 h and subsequently concentrated under reduced pressure to about 100 mL. The concentrated residue was diluted with ethyl acetate (AcOEt, 100 mL) and washed with saturated aqueous sodium bicarbonate (NaHCO3) (2 x 150 mL). The aqueous phases were combined, saturated with sodium bicarbonate and then back-extracted with ethyl acetate (2 × 100 mL). All organic phases were combined, washed with saturated brine (100 mL), dried over anhydrous sodium sulfate (Na2SO4), and concentrated under reduced pressure to remove the solvent. Purification by fast column chromatography (eluent: dichloromethane solution in 2.5% methanol) afforded 6-fluoroimidazo[1,2-a]pyridine as a milky white solid (8.7 g, 72% yield). Mass spectrum (M + H)+ m/z = 137.

References

[1] Patent: EP2210891, 2010, A1. Location in patent: Page/Page column 71

Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) Suppliers

Wuhan Chemwish Technology Co., Ltd
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Adamas Reagent, Ltd.
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SuZhou ShiYa Biopharmaceuticals, Inc.
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9ding chemical ( Shanghai) Limited
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ShangHai AmK Pharmaceutical Technology Co., Ltd.
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Shanghai HuanChuan Industry Co.,Ltd.
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View Lastest Price from Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) manufacturers

Career Henan Chemical Co
Product
Imidazo[1,2-a]pyridine, 6-fluoro- (9CI) 139022-27-8
Price
US $8.80/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
100kg
Release date
2019-07-04