ChemicalBook > CAS DataBase List > 4-(4-Nitrophenyl)azoresorcinol

4-(4-Nitrophenyl)azoresorcinol

Product Name
4-(4-Nitrophenyl)azoresorcinol
CAS No.
74-39-5
Chemical Name
4-(4-Nitrophenyl)azoresorcinol
Synonyms
MAGNESON;MagnesonⅠ;AZO VIOLET;MAGNESON I;MagnesonIGr;MagnesonIiGr;p-diazviolet;MagnesonⅠ, AR;Magneson I AR;AZOVIOLET BENZENE
CBNumber
CB0106591
Molecular Formula
C12H9N3O4
Formula Weight
259.22
MOL File
74-39-5.mol
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4-(4-Nitrophenyl)azoresorcinol Property

Melting point:
195-200 °C (dec.)(lit.)
Boiling point:
402.47°C (rough estimate)
Density 
1.3450 (rough estimate)
refractive index 
1.5700 (estimate)
storage temp. 
Store below +30°C.
form 
Powder
pka
8.05±0.35(Predicted)
color 
Orange-red to red
Odor
Odorless
Appearance
Red, Orange or Red-Orange Powder
Water Solubility 
Soluble in dilute sodium hydroxide. Insoluble in water.
λmax
432 nm
Merck 
14,5695
BRN 
674709
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases.
CAS DataBase Reference
74-39-5(CAS DataBase Reference)
EPA Substance Registry System
1,3-Benzenediol, 4-[(4-nitrophenyl)azo]- (74-39-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
VH2810000
TSCA 
Yes
HS Code 
29270000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
114669
Product name
4-(4-Nitrophenylazo)resorcinol
Purity
Dye content 90%
Packaging
25g
Price
$67.2
Updated
2024/03/01
Sigma-Aldrich
Product number
8.41713
Product name
4-(4-Nitrophenylazo)-resorcinol
Purity
for synthesis
Packaging
25G
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
114669
Product name
4-(4-Nitrophenylazo)resorcinol
Purity
Dye content 90%
Packaging
100g
Price
$219
Updated
2024/03/01
TCI Chemical
Product number
N0135
Product name
Magneson
Packaging
1g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
N0135
Product name
Magneson
Packaging
25g
Price
$39
Updated
2024/03/01
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4-(4-Nitrophenyl)azoresorcinol Chemical Properties,Usage,Production

Description

Oxygen violet can be prepared by one-step reaction of p-nitroaniline and 1,3-benzenediol. Azo violet can be used to prepare an azobenzene photochromic liquid crystal compound. Photochromic liquid crystal compounds have both photochromic properties and liquid crystallinity, which has become a research hotspot in the field of information storage. Azobenzene-based liquid crystals are the most interesting photochromic liquid crystal materials in recent years due to their unique photoinduced cis-trans isomerism. Azobenzene compounds undergo reversible cis-trans isomerization under the action of light, which makes them have great potential applications in many aspects such as optical storage, photo-holography and optical information processing.

Chemical Properties

dark red to brown crystalline powder

Uses

It is a derivitized resorcinol dye compound with an absorption maximum of 432 nm. Used as a pH indicator.

Uses

4-(4-Nitrophenyl)azoresorcinol is used for the detection of magnesium with which it yields a bright blue color in alkaline solution and it also used to determine molybdenum with which it forms a red-violet complex: Nikitina, Andrianova, C.A. 75, 136789v (1971).

Definition

ChEBI: 4-(4-nitrophenylazo)resorcinol is an azobenzene in which the phenyl rings are 4-nitro- and 2,4-dihydroxy-substituted respectively. It is a member of resorcinols, a C-nitro compound and a member of azobenzenes.

Biochem/physiol Actions

4-(4-Nitrophenylazo)resorcinol is a pH indicator.

Purification Methods

Crystallise the dye from EtOH. [Beilstein 16 H 181, 16 IV 1266.]

4-(4-Nitrophenyl)azoresorcinol Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(4-Nitrophenyl)azoresorcinol manufacturers

Hebei Chuanghai Biotechnology Co,.LTD
Product
4-(4-Nitrophenylazo)resorcinol 74-39-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-22
Hebei Fengjia New Material Co., Ltd
Product
4-(4-Nitrophenyl)azoresorcinol 74-39-5
Price
US $4.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2024-08-08
Shaanxi Dideu Medichem Co. Ltd
Product
4-(4-Nitrophenyl)azoresorcinol 74-39-5
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10
Release date
2024-08-04

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