Uses
ChemicalBook > CAS DataBase List > 6-Chloro-imidazo[1,2-a]pyrazine

6-Chloro-imidazo[1,2-a]pyrazine

Uses
Product Name
6-Chloro-imidazo[1,2-a]pyrazine
CAS No.
76537-23-0
Chemical Name
6-Chloro-imidazo[1,2-a]pyrazine
Synonyms
6-Chloro-imidazo[1,2-a]pyrazine;Imidazo[1,2-a]pyrazine, 6-chloro-
CBNumber
CB01113381
Molecular Formula
C6H4ClN3
Formula Weight
153.57
MOL File
76537-23-0.mol
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6-Chloro-imidazo[1,2-a]pyrazine Property

Melting point:
137-138℃
Density 
1.51
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
2.68±0.30(Predicted)
Appearance
Light yellow to brown Solid
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C381690
Product name
6-Chloroimidazo[1,2-a]pyrazine
Packaging
50mg
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
C12875
Product name
6-Chloroimidazo[1,2-a]pyrazine
Purity
95%
Packaging
1g
Price
$40
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-5-J0
Product name
6-Chloroimidazo[1,2-a]pyrazine
Packaging
250mg
Price
$48
Updated
2021/12/16
SynQuest Laboratories
Product number
3H32-5-J0
Product name
6-Chloroimidazo[1,2-a]pyrazine
Packaging
5G
Price
$576
Updated
2021/12/16
AK Scientific
Product number
W8334
Product name
6-Chloroimidazo[1,2-a]pyrazine
Packaging
1g
Price
$74
Updated
2021/12/16
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6-Chloro-imidazo[1,2-a]pyrazine Chemical Properties,Usage,Production

Uses

6-Chloroimidazole[1,2A]pyrazine is a heterocyclic derivative that can be used as a pharmaceutical intermediate.

Synthesis

33332-29-5

2032-35-1

76537-23-0

2-Amino-5-chloropyrazine (2.6 g, 20 mmol) and 2-bromo-1,1-diethoxyethane (12.0 g, 60.89 mmol) were used as starting materials and dissolved in 30 mL of isopropanol. Subsequently, hydrogen bromide solution (10.5 g, 62.22 mmol) was added to the reaction system and the reaction was stirred at 80°C overnight. Upon completion of the reaction, the mixture was cooled to room temperature and the pH was adjusted with sodium bicarbonate to 8. Next, extraction was carried out with dichloromethane, the organic phases were separated and combined, and the crude product was concentrated under reduced pressure. Purification by Combi-flash fast column chromatography (eluent ratio: dichloromethane:methanol = 90:10:70:30) afforded a brown solid product, 6-chloroimidazo[1,2A]pyrazine (2.3 g), in a yield of 49.75% and a purity of 96.63%. The product did not need further purification and could be used directly in the subsequent reaction.

References

[1] Patent: CN105524068, 2016, A. Location in patent: Paragraph 0286; 0287
[2] Journal of Medicinal Chemistry, 1983, vol. 26, # 3, p. 357 - 363

6-Chloro-imidazo[1,2-a]pyrazine Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Chloro-imidazo[1,2-a]pyrazine Suppliers

J & K SCIENTIFIC LTD.
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Pure Chemistry Scientific Inc.
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Kohn & Shawn Pharmatech Co.,Ltd
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9ding chemical ( Shanghai) Limited
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View Lastest Price from 6-Chloro-imidazo[1,2-a]pyrazine manufacturers

Shanghai Rlavie Technology Co ltd
Product
6-Chloro-imidazo[1,2-a]pyrazine 76537-23-0
Price
US $0.00-0.00/kg
Min. Order
0.0001kg
Purity
98%minNMR
Supply Ability
50kg/month
Release date
2022-05-10