METHYL-2METHYL-6-NITRO-BENZOATE
- Product Name
- METHYL-2METHYL-6-NITRO-BENZOATE
- CAS No.
- 61940-22-5
- Chemical Name
- METHYL-2METHYL-6-NITRO-BENZOATE
- Synonyms
- METHYL-2METHYL-6-NITRO-BENZOATE;2-Methyl-6-nitrobenzoic Acid Methyl Ester;Benzoic acid, 2-Methyl-6-nitro-, Methyl ester
- CBNumber
- CB01119075
- Molecular Formula
- C9H9NO4
- Formula Weight
- 195.17
- MOL File
- 61940-22-5.mol
METHYL-2METHYL-6-NITRO-BENZOATE Property
- Boiling point:
- 283.4±20.0 °C(Predicted)
- Density
- 1?+-.0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DCM, Methanol
- form
- Solid
- color
- Brown
Safety
- HS Code
- 2916310090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M320200
- Product name
- 2-Methyl-6-nitrobenzoicAcidMethylEster
- Packaging
- 1g
- Price
- $100
- Updated
- 2021/12/16
- Product number
- CS-W006451
- Product name
- Methyl2-methyl-6-nitrobenzoate
- Purity
- ≥97.0%
- Packaging
- 5g
- Price
- $120
- Updated
- 2021/12/16
- Product number
- OR301028
- Product name
- Methyl2-methyl-6-nitrobenzoate
- Packaging
- 5g
- Price
- $128
- Updated
- 2021/12/16
- Product number
- OR301028
- Product name
- Methyl2-methyl-6-nitrobenzoate
- Packaging
- 1g
- Price
- $44
- Updated
- 2021/12/16
- Product number
- 4754-1-02
- Product name
- Methyl 2-methyl-6-nitrobenzoate
- Purity
- 95%
- Packaging
- 1g
- Price
- $48
- Updated
- 2021/12/16
METHYL-2METHYL-6-NITRO-BENZOATE Chemical Properties,Usage,Production
Uses
2-Methyl-6-nitrobenzoic Acid Methyl Ester is an ester derivative of 2-Methyl-nitrobenzoic Acid (M325545), an derivative of Anthranilic Acid (A679220).
Synthesis
13506-76-8
74-88-4
61940-22-5
Step 1) Synthesis of methyl 2-methyl-6-nitrobenzoate (2): 2-methyl-6-nitrobenzoic acid (1; 10 g, 55.2 mmol) was dissolved in 200 mL of methyl ethyl ketone, iodomethane (17.2 mL, 276.0 mmol) and anhydrous potassium carbonate (38.1 g, 276.0 mmol) were added. The reaction mixture was stirred under reflux conditions for 18 hours. Upon completion of the reaction, the mixture was cooled to room temperature and filtered. The filtrate was diluted with ethyl acetate (300 mL), washed sequentially with water (2 x 50 mL) and saturated saline, dried over anhydrous sodium sulfate, and concentrated under reduced pressure to give 10.80 g of methyl 2-methyl-6-nitrobenzoate (2). Mass spectrometry (ESI) analysis: the calculated value of C9H9NO4 was 195.05 and the measured value was 196 [M + H].
References
[1] Chemical Communications, 2005, # 44, p. 5583 - 5585
[2] Chemistry - A European Journal, 2009, vol. 15, # 24, p. 5956 - 5968
[3] Patent: US2011/251395, 2011, A1. Location in patent: Page/Page column 15
[4] Patent: US2005/49253, 2005, A1. Location in patent: Page/Page column 25-26
[5] Patent: US2005/54670, 2005, A1. Location in patent: Page/Page column 27
METHYL-2METHYL-6-NITRO-BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL-2METHYL-6-NITRO-BENZOATE manufacturers
- Product
- METHYL-2METHYL-6-NITRO-BENZOATE 61940-22-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-12-19