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2-METHYL-6-NITROBENZOIC ANHYDRIDE

Product Name
2-METHYL-6-NITROBENZOIC ANHYDRIDE
CAS No.
434935-69-0
Chemical Name
2-METHYL-6-NITROBENZOIC ANHYDRIDE
Synonyms
MNBA;6-NITRO-O-TOLUIC ANHYDRIDE;6-Nitro-o-toluic Anhydride MNBA;2-METHYL-6-NITROBENZOIC ANHYDRIDE;2-Methyl-6-nitrobenzonic Anhydride;2-Methyl-6-nitrobenzoicAnhydride>2-Methyl-6-nitrobenzoic anhydride 97%;2-Methyl-6-nitrobenzoic acid anhydride;2-Methyl-6-Nitrobenzoic Anhydride(MNBA);Benzoic acid, 2-methyl-6-nitro-, 1,1'-anhydride
CBNumber
CB5686777
Molecular Formula
C16H12N2O7
Formula Weight
344.28
MOL File
434935-69-0.mol
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2-METHYL-6-NITROBENZOIC ANHYDRIDE Property

Melting point:
173-177 °C
Boiling point:
559.4±50.0 °C(Predicted)
Density 
1.416±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
very faint turbidity in hot Toluene
form 
powder to crystal
color 
White to Yellow to Orange
InChI
InChI=1S/C16H12N2O7/c1-9-5-3-7-11(17(21)22)13(9)15(19)25-16(20)14-10(2)6-4-8-12(14)18(23)24/h3-8H,1-2H3
InChIKey
YEKPNMQQSPHKBP-UHFFFAOYSA-N
SMILES
C(C1C(=CC=CC=1N(=O)=O)C)(=O)OC(C1C(=CC=CC=1N(=O)=O)C)=O
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29163990
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
681059
Product name
2-Methyl-6-nitrobenzoic anhydride
Purity
97%
Packaging
1g
Price
$95.9
Updated
2025/07/31
Sigma-Aldrich
Product number
681059
Product name
2-Methyl-6-nitrobenzoic anhydride
Purity
97%
Packaging
10g
Price
$509
Updated
2025/07/31
TCI Chemical
Product number
M1439
Product name
2-Methyl-6-nitrobenzoic Anhydride
Purity
>98.0%(T)
Packaging
1g
Price
$56
Updated
2025/07/31
TCI Chemical
Product number
M1439
Product name
2-Methyl-6-nitrobenzoic Anhydride
Purity
>98.0%(T)
Packaging
5g
Price
$178
Updated
2025/07/31
TCI Chemical
Product number
M1439
Product name
2-Methyl-6-nitrobenzoic Anhydride
Purity
>98.0%(T)
Packaging
25g
Price
$628
Updated
2025/07/31
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2-METHYL-6-NITROBENZOIC ANHYDRIDE Chemical Properties,Usage,Production

Uses

2-Methyl-6-nitrobenzoic anhydride can be used:

  • As a versatile lactonization reagent applicable in the preparation of varieties of macrolide natural products and lactones.
  • As a reaction promoter in the synthesis of carboxamide derivatives by using corresponding amines and carboxylic acids.
  • In the total synthesis of GRP78 inhibitor prunustatin A, antifungal compound (3R,16E,20E,23R)-(?)-eushearilide and an antiobestic drug tetrahydrolipstatin.

General Description

2-Methyl-6-nitrobenzoic anhydride is a reagent employed as a coupling promoter in the synthesis of amides, lactones, esters, and peptides.

2-METHYL-6-NITROBENZOIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYL-6-NITROBENZOIC ANHYDRIDE Suppliers

Nanjing Datang Pharmaceutical Technology Co., Ltd.
Tel
025-84341491 13951930983
Fax
025-84341491
Email
821832400@qq.com
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China
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J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
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96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
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China
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40228
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
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021-67121385
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Sales-CN@TCIchemicals.com
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China
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24529
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Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
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sales8178@energy-chemical.com
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China
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Shanghai Boc Chemical Co.,Ltd
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021-34975603-808 18721111801
Fax
+86-21-34975602-805
Email
sales@bocpharma.com
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China
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1003
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Shanghai Hanhong Scientific Co.,Ltd.
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021-54306202 13764082696
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info@hanhongsci.com
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China
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42934
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Hunan Hui Bai Shi Biotechnology Co., Ltd.
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0731-85526065 13308475853
Email
ivy@hnhbsj.com
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China
ProdList
7247
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Wuhan ariel chemical Co., LTD.
Tel
18986259541 18986259541
Fax
027-87840182
Email
sales@3stc.com
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China
ProdList
3744
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58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66113011 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19906
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View Lastest Price from 2-METHYL-6-NITROBENZOIC ANHYDRIDE manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
2-METHYL-6-NITROBENZOIC ANHYDRIDE 434935-69-0
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-10-10
Career Henan Chemical Co
Product
2-METHYL-6-NITROBENZOIC ANHYDRIDE 434935-69-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2018-08-15

434935-69-0, 2-METHYL-6-NITROBENZOIC ANHYDRIDERelated Search:


  • 6-NITRO-O-TOLUIC ANHYDRIDE
  • 2-METHYL-6-NITROBENZOIC ANHYDRIDE
  • 2-methyl-6-nitrobenzoic acid [(2-methyl-6-nitrophenyl)-oxomethyl] ester
  • 2-Methyl-6-nitrobenzoic anhydride 97%
  • 2-Methyl-6-nitrobenzoic acid anhydride
  • MNBA
  • 2-Methyl-6-Nitrobenzoic Anhydride(MNBA)
  • 6-Nitro-o-toluic Anhydride MNBA
  • 2-Methyl-6-nitrobenzonic Anhydride
  • 2-Methyl-6-nitrobenzoicAnhydride&gt
  • Benzoic acid, 2-methyl-6-nitro-, 1,1'-anhydride
  • 434935-69-0
  • C16H12N2O7
  • Organic Building Blocks
  • Carboxylic Acid Anhydrides
  • Carbonyl Compounds
  • Building Blocks
  • Condensation & Active Esterification
  • Condensation & Active Esterification
  • Synthetic Organic Chemistry