ChemicalBook > CAS DataBase List > 2-METHYL-6-NITROBENZOIC ANHYDRIDE

2-METHYL-6-NITROBENZOIC ANHYDRIDE

Product Name: 2-METHYL-6-NITROBENZOIC ANHYDRIDE
CAS No.: 434935-69-0
Chemical Name: 2-METHYL-6-NITROBENZOIC ANHYDRIDE
Synonyms: MNBA;6-NITRO-O-TOLUIC ANHYDRIDE;6-Nitro-o-toluic Anhydride MNBA;2-METHYL-6-NITROBENZOIC ANHYDRIDE;2-Methyl-6-nitrobenzonic Anhydride;2-Methyl-6-nitrobenzoicAnhydride>2-Methyl-6-nitrobenzoic anhydride 97%;2-Methyl-6-nitrobenzoic acid anhydride;2-Methyl-6-Nitrobenzoic Anhydride(MNBA);Benzoic acid, 2-methyl-6-nitro-, 1,1'-anhydride
CBNumber: CB5686777
Molecular Formula: C16H12N2O7
Formula Weight: 344.28
MOL File: 434935-69-0.mol

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2-METHYL-6-NITROBENZOIC ANHYDRIDE Property

Melting point:: 173-177 °C
Boiling point:: 559.4±50.0 °C(Predicted)
Density: 1.416±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: very faint turbidity in hot Toluene
form: powder to crystal
color: White to Yellow to Orange
InChI: InChI=1S/C16H12N2O7/c1-9-5-3-7-11(17(21)22)13(9)15(19)25-16(20)14-10(2)6-4-8-12(14)18(23)24/h3-8H,1-2H3
InChIKey: YEKPNMQQSPHKBP-UHFFFAOYSA-N
SMILES: C(C1C(=CC=CC=1N(=O)=O)C)(=O)OC(C1C(=CC=CC=1N(=O)=O)C)=O

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 681059
Product name: 2-Methyl-6-nitrobenzoic anhydride
Purity: 97%
Packaging: 1g
Price: $95.9
Updated: 2025/07/31

Sigma-Aldrich

Product number: 681059
Product name: 2-Methyl-6-nitrobenzoic anhydride
Purity: 97%
Packaging: 10g
Price: $509
Updated: 2025/07/31

TCI Chemical

Product number: M1439
Product name: 2-Methyl-6-nitrobenzoic Anhydride
Purity: >98.0%(T)
Packaging: 1g
Price: $56
Updated: 2025/07/31

TCI Chemical

Product number: M1439
Product name: 2-Methyl-6-nitrobenzoic Anhydride
Purity: >98.0%(T)
Packaging: 5g
Price: $178
Updated: 2025/07/31

TCI Chemical

Product number: M1439
Product name: 2-Methyl-6-nitrobenzoic Anhydride
Purity: >98.0%(T)
Packaging: 25g
Price: $628
Updated: 2025/07/31

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2-METHYL-6-NITROBENZOIC ANHYDRIDE Chemical Properties,Usage,Production

Uses

2-Methyl-6-nitrobenzoic anhydride can be used:

As a versatile lactonization reagent applicable in the preparation of varieties of macrolide natural products and lactones.
As a reaction promoter in the synthesis of carboxamide derivatives by using corresponding amines and carboxylic acids.
In the total synthesis of GRP78 inhibitor prunustatin A, antifungal compound (3R,16E,20E,23R)-(?)-eushearilide and an antiobestic drug tetrahydrolipstatin.

General Description

2-Methyl-6-nitrobenzoic anhydride is a reagent employed as a coupling promoter in the synthesis of amides, lactones, esters, and peptides.

2-METHYL-6-NITROBENZOIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-METHYL-6-NITROBENZOIC ANHYDRIDE Suppliers

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View Lastest Price from 2-METHYL-6-NITROBENZOIC ANHYDRIDE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: 2-METHYL-6-NITROBENZOIC ANHYDRIDE 434935-69-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000KGS
Release date: 2025-10-10

Career Henan Chemical Co

Product: 2-METHYL-6-NITROBENZOIC ANHYDRIDE 434935-69-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200KG
Release date: 2018-08-15

434935-69-0, 2-METHYL-6-NITROBENZOIC ANHYDRIDERelated Search:

2-METHYL-6-NITROBENZOIC ACID Benzoic anhydride METHYL-2METHYL-6-NITRO-BENZOATE 2-METHYL-6-NITROBENZOIC ANHYDRIDE 3-Methyl-4-nitrobenzoic acid Methyl 5-bromo-2-hydroxy-3-nitrobenzenecarboxylate 3-Methyl-2-nitrobenzoic acid 4-Nitrobenzoic acid

6-NITRO-O-TOLUIC ANHYDRIDE

2-METHYL-6-NITROBENZOIC ANHYDRIDE

2-methyl-6-nitrobenzoic acid [(2-methyl-6-nitrophenyl)-oxomethyl] ester

2-Methyl-6-nitrobenzoic anhydride 97%

2-Methyl-6-nitrobenzoic acid anhydride

MNBA

2-Methyl-6-Nitrobenzoic Anhydride(MNBA)

6-Nitro-o-toluic Anhydride MNBA

2-Methyl-6-nitrobenzonic Anhydride

2-Methyl-6-nitrobenzoicAnhydride&gt

Benzoic acid, 2-methyl-6-nitro-, 1,1'-anhydride

434935-69-0

C16H12N2O7

Organic Building Blocks

Carboxylic Acid Anhydrides

Carbonyl Compounds

Building Blocks

Condensation & Active Esterification

Synthetic Organic Chemistry