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Erucamide

Product Name
Erucamide
CAS No.
112-84-5
Chemical Name
Erucamide
Synonyms
ERUCAMIDE;ERUCYLAMIDE;13-DOCOSENAMIDE;13Z-DOCOSENAMIDE;(Z)-docos-13-enamide;ERUCIC AMIDE;(z)-13-docosenamide;BYK-AT204;Erucic acid amide;CIS-13-DOCOSENAMIDE
CBNumber
CB0136080
Molecular Formula
C22H43NO
Formula Weight
337.58
MOL File
112-84-5.mol
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Erucamide Property

Melting point:
75-85 °C 79-81 °C (lit.)
Boiling point:
473.86°C (rough estimate)
Density 
0.9417 (rough estimate)
vapor pressure 
0-0Pa at 25℃
refractive index 
1.5614 (estimate)
Flash point:
230 °C
storage temp. 
-20°C
solubility 
Soluble in DMSO (up to at lease 40 mg/ml) or in Water (up to at least 25 mg/ml with warming)
form 
solid
pka
16.61±0.40(Predicted)
color 
Off-white
Water Solubility 
PRACTICALLY INSOLUBLE
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
UAUDZVJPLUQNMU-KTKRTIGZSA-N
LogP
8
CAS DataBase Reference
112-84-5(CAS DataBase Reference)
NIST Chemistry Reference
13-Docosenamide, (z)-(112-84-5)
EPA Substance Registry System
13-Docosenamide, (13Z)- (112-84-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
1
HS Code 
29241990
Hazardous Substances Data
112-84-5(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
280577
Product name
cis-13-Docosenoamide
Packaging
5g
Price
$53
Updated
2024/03/01
Sigma-Aldrich
Product number
PHR3088
Product name
Plastic Additive 13
Purity
pharmaceutical secondary standard, certified reference material
Packaging
200MG
Price
$201
Updated
2024/03/01
Sigma-Aldrich
Product number
1545045
Product name
Plastic additive 13
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
100mg
Price
$436
Updated
2024/03/01
Sigma-Aldrich
Product number
90082
Product name
Erucamide
Purity
analytical standard
Packaging
25MG
Price
$62.8
Updated
2022/05/15
TCI Chemical
Product number
D1008
Product name
Erucamide
Purity
>85.0%(GC)
Packaging
25g
Price
$51
Updated
2024/03/01
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Erucamide Chemical Properties,Usage,Production

Description

Erucamide is also known as 13-Docosenamide or Erucylamide. It is in the form of white flakes or beads. It is soluble in isopropanol, slightly soluble in alcohol and acetone.1 In industry, cis-13-docosenoamide is used in the formulations of anti-adhesive agents, lubricants, and lubricant additives to reduce their friction coefficient and to make films easier to handle.2 It is used as a standard to determine fatty acid amides in polyethylene packaging film by GC/MS.3

Chemical Properties

Erucamide is a fatty acid amide derived from erucic acid, which is found in vegetable oil. It is a odorless waxy solid that can dissolve in isopropanol and has low solubility in alcohol and acetone. It is also combustible. Its molecular structure consists of a long unsaturated C22 chain and a polar amine group, which gives it strong surface polarity, a high melting point, and good thermal stability. Because of these properties, it finds extensive applications in industries such as plastics, rubber, printing, and machinery.

Uses

Erucamide is primarily used as a polymer additive, with plastic additive 21 is a plasticizer; used in preparation of natural mineral modified degradable polymer flame-retardant composite material.

Definition

Erucamide is a primary fatty amide resulting from the formal condensation of the carboxy group of erucic acid with ammonia. It is commonly used as a slip additive in the plastic manufacturing industry. It has a role as a human metabolite, a rat metabolite, a mammalian metabolite, a plant metabolite and an EC 3.1.1.7 (acetylcholinesterase) inhibitor. It is functionally related to an erucic acid.

Preparation

Erucamide is prepared by reaction of erucic acid with anhydrous ammonia. The reaction of erucic acid with anhydrous ammonia is as follows: C22H42O2 + NH3 → C22H43NO2.

General Description

Erucamide is a migratory additive that is commonly placed in polyolefin films to reduce their coefficient of friction (COF), a good attribute for high speed packaging operations.

Biological Activity

13-Docosenamide is the amide of docosenoic acid. It was first identified in the cerebrospinal fluid of sleep-deprived cats. It has also been detected in the cerebrospinal fluid of rats and humans. 13-Docosenamide causes reduced mobility and slightly lessened awareness in rats, whereas 9-octadecenamide induces physiological sleep.

References

[1] MIAO-MIAO LI . Antidepressant and anxiolytic-like behavioral effects of erucamide, a bioactive fatty acid amide, involving the hypothalamus–pituitary–adrenal axis in mice[J]. Neuroscience Letters, 2017, 640: Pages 6-12. DOI:10.1016/j.neulet.2016.12.072.
[2] LIEROP B V, CASTLE L, FEIGENBAUM A, et al. Spectra for the Identification of Additives in Food Packaging[C]. 1998: 0. DOI:10.1007/978-94-011-5222-8.
[3] https://pubchem.ncbi.nlm.nih.gov/compound/Erucylamide#section=Use-and-Manufacturing
[4] https://www.sigmaaldrich.com/catalog/product/aldrich/280577?lang=de&region=DE
[5] I. QUIJADA-GARRIDO. Desorption of Erucamide Vapor in Vacuum from Erucamide/Isotactic Polypropylene Films 1[J]. Macromolecules, 1996, 29 27: 8791-8797. DOI:10.1021/ma961065i.

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Erucamide Suppliers

Young's Corporation
Tel
--
Fax
--
Country
South Korea
ProdList
11
Advantage
50
CHEMICAL LAND21
Tel
--
Fax
--
Email
sales21@chemicalland21.com
Country
South Korea
ProdList
6303
Advantage
74
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View Lastest Price from Erucamide manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Erucamide 112-84-5
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-16
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Erucamide 112-84-5
Price
US $1000.00-800.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-16
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Erucamide 112-84-5
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-15

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