ChemicalBook > CAS DataBase List > 2,2-Diphenylacetic acid

2,2-Diphenylacetic acid

Product Name
2,2-Diphenylacetic acid
CAS No.
117-34-0
Chemical Name
2,2-Diphenylacetic acid
Synonyms
DIPHENYLACETIC ACID;DPAA;2,2-diphenylacetate;'LGC' (2406);iphenylaceticaci;diphenyl-aceticaci;RARECHEM AL BO 1083;DiphenyleaceticAcid;Biphenylacetic acid;diphenylethanoicacid
CBNumber
CB0153782
Molecular Formula
C14H12O2
Formula Weight
212.24
MOL File
117-34-0.mol
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2,2-Diphenylacetic acid Property

Melting point:
147-149 °C(lit.)
Boiling point:
195°C 25mm
Density 
1,257 g/cm3
vapor pressure 
0.001Pa at 25℃
refractive index 
1.6000 (estimate)
Flash point:
195°C/25mm
storage temp. 
Sealed in dry,Room Temperature
solubility 
0.13g/l
form 
Crystalline Powder
pka
3.94(at 25℃)
color 
White to creamy-white
PH
3.8 (H2O, 20℃)(saturated solution)
Water Solubility 
Slightly soluble in water(0.13g/L).
Merck 
14,3316
BRN 
1910978
InChIKey
PYHXGXCGESYPCW-UHFFFAOYSA-N
LogP
3.17 at 25℃
CAS DataBase Reference
117-34-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzeneacetic acid, «alpha»-phenyl-(117-34-0)
EPA Substance Registry System
Benzeneacetic acid, .alpha.-phenyl- (117-34-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-36/37/38
Safety Statements 
24/25-36/37-26
WGK Germany 
2
RTECS 
AH2515000
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29163900
Toxicity
mouse,LD50,intraperitoneal,500mg/kg (500mg/kg),Farmaco, Edizione Scientifica. Vol. 13, Pg. 286, 1958.
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
D204307
Product name
Diphenylacetic acid
Purity
99%
Packaging
5g
Price
$21.9
Updated
2024/03/01
Sigma-Aldrich
Product number
D204307
Product name
Diphenylacetic acid
Purity
99%
Packaging
100g
Price
$99.6
Updated
2024/03/01
TCI Chemical
Product number
D0869
Product name
Diphenylacetic Acid
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
D0869
Product name
Diphenylacetic Acid
Purity
>98.0%(HPLC)(T)
Packaging
100g
Price
$92
Updated
2024/03/01
Alfa Aesar
Product number
A11489
Product name
Diphenylacetic acid, 99%
Packaging
100g
Price
$55.9
Updated
2024/03/01
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2,2-Diphenylacetic acid Chemical Properties,Usage,Production

Chemical Properties

white to creamy-white crystalline powder

Uses

Kinetic resolution of racemic 1-heteroarylalkanols by asymmetric esterification using diphenylacetic acid with pivalic anhydride and a chiral acyl-transfer catalyst is described. Molecular crystal of acridine and diphenylacetic acid and its absolute asymmetric photodecarboxylating condensation generates chirality in a two-component. The activation parameters for the racemization of a series of ortho-alkyl-substituted diphenylacetic acids are determined.

Definition

ChEBI: A monocarboxylic acid that is acetic acid where the methyl hydrogens have been replaced by two phenyl groups respectively.

Synthesis Reference(s)

Journal of the American Chemical Society, 69, p. 2325, 1947 DOI: 10.1021/ja01202a023
Synthetic Communications, 17, p. 1919, 1987 DOI: 10.1080/00397918708057804

Purification Methods

Crystallise the acid from *benzene, H2O or aqueous 50% EtOH. [Beilstein 9 H 673, 9 IV 2492.]

2,2-Diphenylacetic acid Preparation Products And Raw materials

Raw materials

Benzilic acid

Preparation Products

DIPHENAMID Flutropium bromide
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2,2-Diphenylacetic acid Suppliers

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View Lastest Price from 2,2-Diphenylacetic acid manufacturers

S&Y Biochem Co.,Ltd
Product
Diphenylacetic acid 117-34-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99
Supply Ability
1000
Release date
2024-10-11
Hebei Fengjia New Material Co., Ltd
Product
2,2-Diphenylacetic acid 117-34-0
Price
US $7.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100000
Release date
2024-08-14
Hebei Weibang Biotechnology Co., Ltd
Product
2,2-Diphenylacetic acid 117-34-0
Price
US $1.00/PCS
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2021-06-15

117-34-0, 2,2-Diphenylacetic acidRelated Search:

Phenylacetic acid Phenyl sulfoxide 2-Phenylacetophenone Triphenylacetic acid 2,2-Diphenylglycine Propantheline bromide 2,2'-DICHLOROBENZILIC ACID Adiphenine hydrochloride Benzilic acid 9-Carboxyfluorene Methyl benzilate METHANTHELINE BROMIDE XANTHENE-9-CARBOXYLIC ACID METHYL DIPHENYLACETATE BENACTYZINE HYDROCHLORIDE ETHYL BENZILATE BIS(2,4-DINITROPHENYL)ACETIC ACID ETHYL ESTER 2-ETHYLTHIO-2,2-DIPHENYLACETIC ACID

  • MONOCARBOXYMETHANEDIPHENYL
  • RARECHEM AL BO 1083
  • A-PHENYLPHENYLACETIC ACID
  • CARBOXYMETHANEDIPHENYL
  • DIPHENYLACETIC ACID
  • DIPHENYLMETHANE-A-CARBOXYLIC ACID
  • DIPHENYLMETHANE-ALPHA-CARBOXYLIC ACID
  • DIPHENYLMETHANECARBOXYLIC ACID
  • DPAA
  • 'LGC' (2406)
  • 2,2-Diphenylacetic acid
  • .alpha.-phenyl-Benzeneaceticacid
  • DIPHENYLACETIC ACID CRYSTALLINE
  • MELTING POINT STANDARD DIPHENYLACETICACI D
  • DiphenyleaceticAcid
  • Biphenylacetic acid
  • Diphenylacetic acid, 99+%
  • Benzeneacetic acid, .alpha.-phenyl-
  • Diphenylacetic acid, 99+% 100GR
  • DIPHENYLACETIC ACID FOR SYNTHESIS
  • alpha-Diphenylacetic acid
  • 2,2-diphenylacetate
  • 1,1-diphenylaceticacid
  • Acetic acid, diphenyl-
  • alpha,alpha-Diphenylacetic acid
  • alpha,alpha-diphenylaceticacid
  • alpha-phenyl-benzeneaceticaci
  • alpha-Toluic acid, alpha-phenyl-
  • diphenyl-aceticaci
  • Diphenylethanoic acid
  • diphenylethanoicacid
  • -Phenylbenzeneaceticacid
  • Two phenylacetic acid
  • Diphenylacetic Acid &gt
  • Benzeneacetic acid, α-phenyl-
  • iphenylaceticaci
  • DIPHENYLACETIC ACID 117-34-0
  • Methadone Impurity 26
  • 117-34-0
  • C6H52CHCO2H
  • C6H42CHCOOH
  • C6H52CHCOOH
  • CARBOXYLIC ACID
  • Carboxylic Acids
  • Carbonyl Compounds
  • C13 to C42+
  • Analytical Chromatography Product Catalog
  • Alphabetic
  • Analytical Standards
  • Building Blocks
  • DIO - DIZ
  • Organic Building Blocks
  • C13 to C42+
  • Pharmaceutical Intermediates
  • Aromatic Phenylacetic Acids and Derivatives
  • C13 to C42+Alphabetic
  • Carbonyl Compounds
  • Carboxylic Acids