ChemicalBook > CAS DataBase List > ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE

ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE

Product Name
ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE
CAS No.
84102-69-2
Chemical Name
ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE
Synonyms
AURORA 22531;5-broMobenzofuran-2-carboxylate;5-bromo-1-benzofuran-2-carboxyL;ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE;5-Bromo-2-(ethoxycarbonyl)-1-benzofuran;Ethyl(5-bromobenzofurane)-2-carboxylate;Ethyl 5-bromobenzo[b]furan-2-carboxylate;ETHYL 5-BROMO-1-BENZOFURAN-2-CARBOXYLATE;ETHYL-5-BROMO-BENZENZOFURAN-2-CARBOXYLATE;5-Bromo-benzofuran-2-carboxylic acid ethyl ester
CBNumber
CB0154097
Molecular Formula
C11H9BrO3
Formula Weight
269.09
MOL File
84102-69-2.mol
More
Less

ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE Property

Melting point:
60-62°
Boiling point:
328.3±22.0 °C(Predicted)
Density 
1.520±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
Appearance
White to off-white Solid
InChI
InChI=1S/C11H9BrO3/c1-2-14-11(13)10-6-7-5-8(12)3-4-9(7)15-10/h3-6H,2H2,1H3
InChIKey
XLJWAHXKBCDQNP-UHFFFAOYSA-N
SMILES
O1C2=CC=C(Br)C=C2C=C1C(OCC)=O
CAS DataBase Reference
84102-69-2
More
Less

Safety

Hazard Codes 
Xi
HazardClass 
IRRITANT
HS Code 
2932990090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

More
Less

N-Bromosuccinimide Price

TRC
Product number
E900623
Product name
Ethyl5-bromobenzofuran-2-carboxylate
Packaging
100mg
Price
$45
Updated
2021/12/16
Usbiological
Product number
449411
Product name
Ethyl 5-bromobenzofuran-2-carboxylate
Packaging
100mg
Price
$305
Updated
2021/12/16
AK Scientific
Product number
J96809
Product name
Ethyl(5-bromobenzofuran)-2-carboxylate
Packaging
250mg
Price
$35
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0026131
Product name
ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE
Purity
95.00%
Packaging
1G
Price
$734.67
Updated
2021/12/16
Apolloscientific
Product number
OR14257
Product name
Ethyl5-bromobenzo[b]furan-2-carboxylate
Packaging
1g
Price
$89
Updated
2021/12/16
More
Less

ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE Chemical Properties,Usage,Production

Uses

Ethyl 5-bromobenzofuran-2-carboxylate

Synthesis

105-36-2

1761-61-1

84102-69-2

5-Bromosalicylaldehyde (5 g, 25 mmol, 1.0 eq.) and cesium carbonate (8.2 g, 25 mmol, 1.0 eq.) were dissolved in 80 ml of DMF and stirred well. Subsequently, ethyl bromoacetate (8.3 g, 50 mmol, 2.0 eq.) was slowly added to the reaction system. The reaction mixture was stirred at room temperature for 30 min. After that, the reaction temperature was increased to 120 °C for 2 hours. The reaction progress was monitored by TLC. After completion of the reaction, the mixture was cooled to room temperature and poured into ice water and stirred vigorously for 30 minutes. The precipitate was collected by filtration, the filter cake was washed with water and dried to give the yellow powdery solid product ethyl 5-bromobenzofuran-2-carboxylate (4 g, 59.7% yield).

References

[1] Patent: CN106478564, 2017, A. Location in patent: Paragraph 0216; 0217; 0218
[2] Patent: CN107383024, 2017, A. Location in patent: Paragraph 0473
[3] Patent: US2004/209865, 2004, A1
[4] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 20, p. 5591 - 5593

ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Sodium Sodium iodide Ethyl bromoacetate Methanol 5-Bromosalicylaldehyde Sodium carbonate

Preparation Products

More
Less

ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE Suppliers

Austria 1 Belgium 1 China 101 Germany 1 India 5 United Kingdom 4 United States 14 Global 127
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
Shanghai Aobo pharmaceutical Technology Co., Ltd
Tel
86-21-51320499
Fax
86-21-51320368
Email
aobo@aobopharm.com
Country
China
ProdList
297
Advantage
57
Hangzhou Yuhao Chemical Technology Co., Ltd
Tel
0571-82693216
Fax
+86-571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
6387
Advantage
52
Shenzhen Pharma Technology Co., Ltd.
Tel
0755-86648230
Fax
0755-86648231
Email
pharma08@sina.com
Country
China
ProdList
166
Advantage
58
Shanghai ZaiQi Bio-Tech Co., Ltd.
Tel
021-54824098, 021-37212705 021-37212706, 13391256916
Fax
021-54824069
Email
sales@chemzq.com
Country
China
ProdList
570
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai Topbiochem Technology Co., Ltd
Tel
021-58170097
Email
info@topbiochem.com
Country
China
ProdList
9510
Advantage
58
ShangHai Wing Chemical Co., Ltd.
Tel
18621196961
Fax
+86-21-51079518
Email
ckzhou@chemwing.com
Country
China
ProdList
22
Advantage
58
Shanghai potentpharm CO.,Ltd
Tel
(86) 21 51969655
Fax
(86) 21 51969655， QQ：33109286， 263541193
Country
China
ProdList
487
Advantage
22
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
SHANGHAI FORTUNE CHEMICAL TECHNOLOGY CO., LTD
Tel
13816107857
Fax
qq: 276312098
Email
sales@fortunechem-sh.com
Country
China
ProdList
984
Advantage
58
Shanghai Hao Yun Chemical Science Co.,Ltd.
Tel
021-68367562 15002147577;
Fax
021-68369562
Email
sales@haoyunchem.com
Country
China
ProdList
457
Advantage
55
Bide Pharmatech Ltd.
Tel
400-164-7117 13681763483
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
39966
Advantage
60
Shanghai ShiXian Chemical Technology Co., Ltd.
Tel
18681884732
Fax
021-51632502
Email
2245256225@qq.com
Country
China
ProdList
1729
Advantage
50
Chemfun Medical Technology(Shanghai) Co., Ltd.
Tel
021-67220633 021-54824098
Fax
+86-21-54824069
Email
chemfun@chemfun.net
Country
China
ProdList
491
Advantage
58
Jiaxing Novartis Chemical Co., Ltd.
Tel
18957373295
Fax
-
Country
China
ProdList
1580
Advantage
58
Hangzhou J&H Chemical Co., Ltd.
Tel
0571-87396432
Fax
0571-87396431
Email
sales@jhechem.com
Country
China
ProdList
14912
Advantage
59
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Amatek Scientific Co. Ltd.
Tel
0512-56316828
Fax
0512-56316826
Email
info@amateksci.com
Country
China
ProdList
28785
Advantage
58
Biokitchen
Tel
021-021-021-31663258 13795219287
Fax
021-31663258
Email
donghuanwen@126.com
Country
China
ProdList
8816
Advantage
58
Capot Chemical Co.,Ltd.
Tel
+86-（0）57185586718; +8613336195806
Fax
+86-571-85864795
Email
sales@capot.com
Country
China
ProdList
29735
Advantage
60
Aikon International Limited
Tel
025-58851090 15955137747
Fax
(6)02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
15949
Advantage
58
SHANGHAI FDC-CHEMICAL CO.,LTD
Tel
021-61469567 13482353728
Fax
021-61161605
Email
sales@fdc-chemical.com
Country
China
ProdList
9721
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 400821072
Fax
021-58955996
Email
malulu@leyan.com
Country
China
ProdList
25000
Advantage
58
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400-6387771-6039 18920764717
Email
sales@heowns.com
Country
China
ProdList
23771
Advantage
60
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Jizhi Biochemical Technology Co. Ltd.
Tel
4009004166/18616739031 18616739031
Email
3007523370@qq.com
Country
China
ProdList
52687
Advantage
58
Shanghai Scochem Technology Co., Ltd.
Tel
021-33758897
Email
sales@scochem.com
Country
China
ProdList
1596
Advantage
58
Shanghai Gugang New Materials Technology Co. Ltd.
Tel
021-51317962
Fax
021-51317962
Email
296935822@qq.com
Country
China
ProdList
986
Advantage
58
Anhui xinying technology co., LTD
Tel
18505585965
Email
sales@xinying-chem.com
Country
China
ProdList
176
Advantage
58
Zhejiang J&C Biological Technology Co.,Limited
Tel
+1-2135480471
Email
sales@sarms4muscle.com
Country
China
ProdList
10473
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
+86-0571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52846
Advantage
58
Henan Weituxi Chemical Technology Co., Ltd.
Tel
0371-63284658 18135795563
Fax
QQ:2885349392
Email
2885349392@qq.com
Country
China
ProdList
9989
Advantage
58
Chemwill Asia Co.,Ltd.
Tel
86-21-51086038
Fax
86-21-51861608
Email
chemwill_asia@126.com
Country
CHINA
ProdList
23912
Advantage
58
Shanghai TenSus Biotechnology Co., Ltd.
Tel
021-50895067 18616507272
Fax
021-50895067
Email
tensus@163.com
Country
China
ProdList
8073
Advantage
58
Chongqing Chemdad Co., Ltd
Tel
+86-023-6139-8061 +86-86-13650506873
Email
sales@chemdad.com
Country
China
ProdList
39927
Advantage
58
Shan Xian Lan Platinum Biotechnology Co., Ltd.
Tel
15854067352
Email
sxqzhg@163.com
Country
China
ProdList
298
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
Taizhou Nanfeng Pharmaceutical Research Institute
Tel
nanfengdrug@163.com; 18616377689
Email
nanfengdrug@163.com
Country
China
ProdList
20009
Advantage
58
Changzhou Kechem Bio-Scientific Co., LTD.
Tel
0519-68985668 13685222090
Fax
qq735434464
Email
sales@kechem.cn
Country
China
ProdList
26028
Advantage
58
Jiaxing Jilat Chemical Co. LTD
Tel
0573-82813639 15157377625
Fax
0573-82813637
Email
sales@jlightchem.com
Country
China
ProdList
165
Advantage
58
Chongqing Kemai Material Technology Co., Ltd
Tel
17830741407
Fax
QQ：2479150351
Email
sales@chem47.com
Country
China
ProdList
1768
Advantage
58
Krain Pharmaceutical Technology CO.,Ltd
Tel
18252089365
Email
Krain_kerun@163.com
Country
China
ProdList
2507
Advantage
58
Suzhou QIHANG Biotechnology Co., Ltd
Tel
18662190603
Email
437347250@qq.com
Country
China
ProdList
4674
Advantage
58
Huaian Jiamu Biotechnology Co., Ltd.
Tel
0517-83187139 18205232085
Email
cai@jiamu-bio.com
Country
China
ProdList
2996
Advantage
58
Shanghai Naiys Biological Technology Co., Ltd
Tel
18321139117
Email
316441092@qq.con
Country
China
ProdList
3003
Advantage
58
TCI (Shanghai) Chemical Trading Co., Ltd.
Tel
021-61109150
Fax
021-61105897
Email
sales@tcisct.com
Country
China
ProdList
29668
Advantage
58
More
Less

View Lastest Price from ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE manufacturers

Career Henan Chemical Co
Product
ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE 84102-69-2
Price
US $100.00/KG
Min. Order
100G
Purity
98%
Supply Ability
500KG
Release date
2018-07-25

84102-69-2, ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATERelated Search:

5-Bromo-1-benzofuran 5-BROMO-BENZOOXAZOLE 5-BROMOBENZO[B]THIOPHENE-2-CARBALDEHYDE 5-bromobenzo[d]isothiazol-3-amine 5-BROMO-1-BENZOTHIOPHENE-2-CARBOXYLIC ACID 5-BROMO-1-BENZOFURAN-2-CARBOXYLIC ACID ETHYL 5-BROMO-4-ISOPROPOXY-3-METHYLBENZOFURAN-2-CARBOXYLATE 5-BROMO-3-METHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER 5-BROMO-3-BROMOMETHYL-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE 3-AMINO-5-BROMO-BENZOFURAN-2-CARBOXYLIC ACID ETHYL ESTER

  • ETHYL 5-BROMO-1-BENZOFURAN-2-CARBOXYLATE
  • ETHYL(5-BROMOBENZOFURAN)-2-CARBOXYLATE
  • AURORA 22531
  • Ethyl(5-bromobenzofurane)-2-carboxylate
  • Ethyl 5-bromobenzo[b]furan-2-carboxylate
  • N-[(E)-(4-fluorophenyl)methylideneamino]-2-[[1-[(2E)-2-[(4-fluorophenyl)methylidene]hydrazinyl]-1-oxopropan-2-yl]thio]propanamide
  • 5-Bromo-benzofuran-2-carboxylic acid ethyl ester
  • 2-Benzofurancarboxylic acid, 5-bromo-, ethyl ester
  • 5-Bromo-2-(ethoxycarbonyl)-1-benzofuran
  • 5-broMobenzofuran-2-carboxylate
  • ETHYL-5-BROMO-BENZENZOFURAN-2-CARBOXYLATE
  • 5-bromo-1-benzofuran-2-carboxyL
  • 84102-69-2