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Ethyl bromoacetate

Product Name
Ethyl bromoacetate
CAS No.
105-36-2
Chemical Name
Ethyl bromoacetate
Synonyms
Antol;ethylbromacetate;hyl bromoacetate;Ethyl bromacetate;ETHYL BROMOACETATE;ethylbromoethanoate;ETHYL 2-BROMOACETATE;bromoacetated’ethyle;ethylmonobromoacetate;thyl monobromoacetate
CBNumber
CB6852654
Molecular Formula
C4H7BrO2
Formula Weight
167
MOL File
105-36-2.mol
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Ethyl bromoacetate Property

Melting point:
-38 °C
Boiling point:
159 °C(lit.)
Density 
1.506 g/mL at 25 °C(lit.)
vapor density 
5.8 (vs air)
vapor pressure 
2.6 mm Hg ( 25 °C)
refractive index 
n20/D 1.451(lit.)
Flash point:
118 °F
storage temp. 
Store below +30°C.
solubility 
water: insoluble
form 
Liquid
color 
Clear
Specific Gravity
1.506
Odor
Pungent odour
Water Solubility 
Miscible with ethanol, acetone, benzene and ethyl ether. Immiscible with water.
BRN 
506456
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, water, strong acids.
InChIKey
PQJJJMRNHATNKG-UHFFFAOYSA-N
CAS DataBase Reference
105-36-2(CAS DataBase Reference)
NIST Chemistry Reference
Acetic acid, bromo-, ethyl ester(105-36-2)
EPA Substance Registry System
Acetic acid, 2-bromo-, ethyl ester (105-36-2)
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Safety

Hazard Codes 
T+
Risk Statements 
26/27/28
Safety Statements 
26-45-7/9-1/2
RIDADR 
UN 1603 6.1/PG 2
WGK Germany 
1
RTECS 
AF6000000
19
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II
HS Code 
29159080
Hazardous Substances Data
105-36-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H300Fatal if swallowed

H310Fatal in contact with skin

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P320Specific treatment is urgent (see … on this label).

P330Rinse mouth.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
133973
Product name
Ethyl bromoacetate
Purity
reagent grade, 98%
Packaging
5g
Price
$35.4
Updated
2021/03/22
Sigma-Aldrich
Product number
133973
Product name
Ethyl bromoacetate
Purity
reagent grade, 98%
Packaging
100g
Price
$36.3
Updated
2021/03/22
Sigma-Aldrich
Product number
8.01636
Product name
Ethyl bromoacetate
Purity
for synthesis
Packaging
250 mL
Price
$85.56
Updated
2021/03/22
Sigma-Aldrich
Product number
8.01636
Product name
Ethyl bromoacetate
Purity
for synthesis
Packaging
1 L
Price
$259
Updated
2021/03/22
Alfa Aesar
Product number
A10448
Product name
Ethyl bromoacetate, 98%
Packaging
100g
Price
$32.4
Updated
2020/06/24
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Ethyl bromoacetate Chemical Properties,Usage,Production

Chemical Properties

Ethyl bromoacetate is a clear, colorless to light-yellow liquid and has a pungent odor. It is insoluble in water, but is soluble in acetone and benzene (Lide, 1999; Lewis, 1997). Ethyl bromoacetate is miscible with ethanol, ethyl ether, and with other oxygenated and aromatic solvents (Ashford, 1994; Lide, 1999). It is partially decomposed by water (Lewis, 1997).

Uses

Ethyl Bromoacetate, is used in the synthesis of metabolites of carcinogenic PAHs. Used in the preparation of steroidal antiestrogens through cyclic condensation. A reactant in the preparation of antim icrobial and antioxidant coumarinyloxymethyl-thiadiazolone.

General Description

A clear, colorless liquid (b.p. 318°F). Flash point 47°C. A lachrymator. Toxic by ingestion, inhalation and skin absorption; a strong irritant of the skin. Insoluble in water and soluble in alcohol, benzene, and ether. Specific gravity of 1.5.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

Ethyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Toxic by ingestion, inhalation, and skin absorption; strong irritant.

Health Hazard

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

Safety Profile

A poison. An irritant to skin, eyes, and mucous membranes. Questionable carcinogen with experimental neoplastigenic data. Flammable liquid when exposed to heat, flame, and oxidizers. Will react with water or steam to produce toxic and corrosive fumes. To fight fire, use water as a fire blanket. When heated to decomposition or on contact with acid or acid fumes, it emits highly toxic fumes of Br-. See also BROMIDES.

Potential Exposure

Used for making pharmaceuticals; as a warning gas in poisonous, odorless gasses; as a tear gas

Shipping

UN1603 Ethyl bromoacetate, Hazard class: 6.1; Labels: 6.1-Poisonous materials.

Purification Methods

Wash the ester with saturated aqueous Na2CO3 (three times), 50% aqueous CaCl2 (three times) and saturated aqueous NaCl (twice). Dry with MgSO4, CaCl2 or CaCO3, and distil it. [Beilstein 2 IV 527.] LACHRYMATORY.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and reducing agents. Esters are generally incompatible with nitrates. Moisture may cause hydrolysis or other forms of decomposition.

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Ethyl bromoacetate Suppliers

Yancheng shengda chemical co. LTD
Tel
Email
yc@creatorchem.com
Country
China
ProdList
1
Advantage
58
Anqing PhiChem Corporation
Tel
0556-5209970
Fax
0556-5209971
Email
salesaq@phichem.com.cn
Country
China
ProdList
36
Advantage
65
Jinxiang Chemical (Danyang) Products Co., Ltd.
Tel
025-86819862
Fax
0086-25-86819859
Email
nancyzong@jinchemical.com
Country
China
ProdList
97
Advantage
74
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028-
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12282
Advantage
60
Credit-Chem Co., Ltd.
Tel
400-821-5857 021-64326257
Fax
021-64393586 QQ;2798200800
Email
credit-chem@foxmail.com
Country
China
ProdList
5229
Advantage
58
Kingfirst Chemical (Nanjing) Co.,Ltd
Tel
+86-025-84522992 84524602 13805186390
Fax
+86 025 84521617
Email
marketing@kingfirstchem.com
Country
China
ProdList
74
Advantage
58
Wuhan Georui Aijiete Technology Co., Ltd.
Email
1294919813@qq.com
Country
China
ProdList
24
Advantage
58
Shandong Chunyu Fine Chemical Co., Ltd.
Tel
13561220159
Email
310796521@qq.com
Country
CHINA
ProdList
173
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96501
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40265
Advantage
62
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View Lastest Price from Ethyl bromoacetate manufacturers

Hebei shuoxi biotechnology co. LTD
Product
Ethyl bromoacetate 105-36-2
Price
US $60.00/KG
Min. Order
10g
Purity
99.8%
Supply Ability
10tons
Release date
2019-10-29
Hebei Miaobian Biotechnology Co., Ltd
Product
Ethylbromoacetate 105-36-2
Price
US $10.00/KG
Min. Order
1KG
Purity
99.99
Supply Ability
10Ton
Release date
2021-03-16
Hebei Henghe Import and Export Trading Co. LTD
Product
Ethyl bromoacetate 105-36-2
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100
Release date
2020-12-17

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