ChemicalBook > CAS DataBase List > N-(1-Cyclohexen-1-yl)morpholine

N-(1-Cyclohexen-1-yl)morpholine

Product Name
N-(1-Cyclohexen-1-yl)morpholine
CAS No.
670-80-4
Chemical Name
N-(1-Cyclohexen-1-yl)morpholine
Synonyms
BNKY018-PG03;AKOS BBS-00000855;Etizolam Impurity 4;Morpholinocyclohexene;1-MORPHOLINOCYCLOHEXENE;4-cyclohexenylmorpholine;N-MORPHOLINO-1-CYCLOHEXENE;1-MORPHOLINO-1-CYCLOHEXENE;1-Morpholin-1-ylcyclohexene;1(1-Cyclohexenyl)morpholine
CBNumber
CB0163684
Molecular Formula
C10H17NO
Formula Weight
167.25
MOL File
670-80-4.mol
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N-(1-Cyclohexen-1-yl)morpholine Property

Boiling point:
118-120 °C10 mm Hg(lit.)
Density 
0.995 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.514(lit.)
Flash point:
155 °F
storage temp. 
2-8°C
pka
6.33±0.20(Predicted)
form 
clear liquid
color 
Colorless to Light yellow to Light orange
BRN 
118696
InChI
InChI=1S/C10H17NO/c1-2-4-10(5-3-1)11-6-8-12-9-7-11/h4H,1-3,5-9H2
InChIKey
IIQFBBQJYPGOHJ-UHFFFAOYSA-N
SMILES
N1(C2CCCCC=2)CCOCC1
CAS DataBase Reference
670-80-4(CAS DataBase Reference)
NIST Chemistry Reference
Morpholine, 4-(1-cyclohexen-1-yl)-(670-80-4)
EPA Substance Registry System
Morpholine, 4-(1-cyclohexen-1-yl)- (670-80-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
F 
9
TSCA 
Yes
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
M87800
Product name
1-Morpholinocyclohexene
Purity
98%
Packaging
25g
Price
$96.8
Updated
2023/06/20
TCI Chemical
Product number
C0956
Product name
1-Morpholino-1-cyclohexene
Purity
>97.0%(GC)(T)
Packaging
25mL
Price
$64
Updated
2025/07/31
TCI Chemical
Product number
C0956
Product name
1-Morpholino-1-cyclohexene
Purity
>97.0%(GC)(T)
Packaging
500mL
Price
$516
Updated
2025/07/31
TRC
Product number
C997913
Product name
4-(Cyclohex-1-en-1-yl)morpholine
Packaging
500mg
Price
$40
Updated
2021/12/16
TRC
Product number
C997913
Product name
4-(Cyclohex-1-en-1-yl)morpholine
Packaging
1g
Price
$50
Updated
2021/12/16
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N-(1-Cyclohexen-1-yl)morpholine Chemical Properties,Usage,Production

Description

1-Morpholinocyclohexene (N-(1-Cyclohexen-1-yl)morpholine) falls under the category of organic compounds called morpholine class of heterocyclic amines. This colorless liquid possesses a distinct amine-like odor and displays remarkable versatility with widespread applications in multiple industries, including agrochemicals and cosmetics. Moreover, it is a valuable solvent, corrosion inhibitor, and integral component in lubricants[1].

Chemical Properties

CLEAR COLOURLESS TO LIGHT YELLOW LIQUID

Synthesis Reference(s)

Synthesis, p. 529, 1984 DOI: 10.1055/s-1984-30893

Synthesis

110-91-8

108-94-1

670-80-4

The general procedure for the synthesis of 1-morpholino-1-cyclohexene from morpholine and cyclohexanone is as follows: to a solution of morpholine (10.5 mL, 0.12 mol, 1.2 eq.) in anhydrous toluene (70 mL) was added cyclohexanone (10.4 mL, 0.10 mol, 1.0 eq.), followed by the addition of p-toluenesulfonic acid (0.20 g, 1.16 mmol. 0.016 eq.) as a catalyst. The reaction mixture was heated to reflux for 5 hours. Upon completion of the reaction, the reaction solution was cooled and subsequently concentrated under reduced pressure to afford the target product 1-morpholino-1-cyclohexene in 85% yield.

References

[1] R. Nesi. “Reactions of 3,5-dimethyl-4-nitroisoxazole with cyclic enamines and 1-diethylaminopropyne.” Heterocycles 32 1 (1991): 1913–1921.

N-(1-Cyclohexen-1-yl)morpholine Preparation Products And Raw materials

Raw materials

Preparation Products

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N-(1-Cyclohexen-1-yl)morpholine Suppliers

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View Lastest Price from N-(1-Cyclohexen-1-yl)morpholine manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
N-(1-Cyclohexen-1-yl)morpholine 670-80-4
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-10-14
Henan Fengda Chemical Co., Ltd
Product
N-(1-Cyclohexen-1-yl)morpholine 670-80-4
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
N-(1-Cyclohexen-1-yl)morpholine 670-80-4
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11

670-80-4, N-(1-Cyclohexen-1-yl)morpholineRelated Search:

Magnesium hydroxide BISNORCHOLENALDEHYDE tert-Butyl (2-(2,2-dimethyl-4H-benzo[d][1,3]dioxin-6-yl)-2-oxoethyl)carbamate CarbaMic acid, [(2R)-2-(2,2-diMethyl-4H-1,3-benzodioxin-6-yl)-2-hydroxyethyl]-, 1,1-diMethylethyl ester 2-Oxazolidinone, 5-(2,2-diMethyl-4H-1,3-benzodioxin-6-yl)-, (5R)- Abiraterone Furan Pyrimidine Ferric sulfate Cyclohexene N-(1-Cyclohexen-1-yl)morpholine 1-(N-MORPHOLINO)-6-OXIMINOCYCLOHEXENE SALOR-INT L140783-1EA 3-MORPHOLIN-4-YLCYCLOHEX-2-EN-1-ONE (3E)-3-(4-CHLOROBENZYLIDENE)-2-MORPHOLIN-4-YLCYCLOHEX-1-ENE-1-CARBALDEHYDE 3-ETHYL-2-((E)-2-[3-((E)-2-[3-ETHYL-1,3-BENZOTHIAZOL-2(3H)-YLIDENE]ETHYLIDENE)-2-(4-MORPHOLINYL)-1-CYCLOHEXEN-1-YL]ETHENYL)-1,3-BENZOTHIAZOL-3-IUM IODIDE SALOR-INT L141666-1EA 5,5-DIMETHYL-3-MORPHOLIN-4-YL-CYCLOHEX-2-ENYLIDENEAMINE

  • N-(1-CYCLOHEXEN-1-YL)MORPHOLINE
  • MORPHOLINE, 4-(1-CYCLOHEXEN-1-YL)-
  • N-MORPHOLINO-1-CYCLOHEXENE
  • 1(1-Cyclohexenyl)morpholine
  • 1-Morpholin-1-ylcyclohexene
  • 4-(1-cyclohexen-1-yl)-morpholin
  • 4-(1-Cyclohexenyl)morpholine
  • Cyclohexanone morpholine enamine
  • 4-CYCLOHEX-1-ENYLMORPHOLINE
  • 4-(CYCLOHEXEN-1-YL)MORPHOLINE
  • 4-(1-CYCLOHEXEN-1-YL)MORPHOLINE
  • 1-(N-MORPHOLINO)CYCLOHEXENE
  • 1-MORPHOLINO-1-CYCLOHEXENE
  • 1-MORPHOLINOCYCLOHEXENE
  • AKOS BBS-00000855
  • 1-(4-MORPHOLINO)CYCLOHEXENE
  • Morpholinocyclohexene
  • N-(cyclohex-1-en-1-yl)morpholine
  • 4-cyclohexenylmorpholine
  • 1-(N-morpholino)cyclohexane
  • N-(Cyclohexen-1-yl)morpholine
  • N-Morpholino-1-cyclohexene,98%
  • 4-(cyclohex-1-en-1-yl)Morpholine
  • 1-Morpholinocyclohexene 98%
  • 4-(1-cyclohexenyl)morpholin-4-ium
  • BNKY018-PG03
  • 1-Morpholino-1-cyclohexene &gt
  • N-(1-Cyclohexen-1-yl)morpholine ISO 9001：2015 REACH
  • Etizolam Impurity 4
  • 670-80-4
  • Building Blocks
  • Heterocyclic Building Blocks
  • Morpholines
  • Aromatic Morpholines
  • Morpholines/Thiomorpholines
  • Building Blocks
  • Chemical Synthesis
  • Heterocyclic Building Blocks
  • Miscellaneous Compounds