(R)-MOP
- Product Name
- (R)-MOP
- CAS No.
- 145964-33-6
- Chemical Name
- (R)-MOP
- Synonyms
- (R)-MOP;R-MOP >=94%;(R)-(+)-MOP;98% (R)-MOP;99% (R)-MOP;(R)-(+)-2-(DiphenyL;phosphino)-2'-methoxy-1,1'-binaphthyL;(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL
- CBNumber
- CB0180962
- Molecular Formula
- C33H25OP
- Formula Weight
- 468.52
- MOL File
- 145964-33-6.mol
(R)-MOP Property
- Melting point:
- 177-179°C
- alpha
- +67° ±2° (c 1, toluene)
- Boiling point:
- 584.1±38.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- almost transparency in Toluene
- form
- Powder
- color
- white
- optical activity
- [α]20/D +94°, c = 0.5 in chloroform
- Sensitive
- air sensitive
- CAS DataBase Reference
- 145964-33-6(CAS DataBase Reference)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P310Immediately call a POISON CENTER or doctor/physician.
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- D2774
- Product name
- (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $699
- Updated
- 2024/03/01
- Product number
- D2774
- Product name
- (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
- Purity
- >98.0%(GC)
- Packaging
- 100mg
- Price
- $144
- Updated
- 2024/03/01
- Product number
- 15-1775
- Product name
- (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
- Packaging
- 100mg
- Price
- $99
- Updated
- 2024/03/01
- Product number
- 15-1775
- Product name
- (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
- Packaging
- 500mg
- Price
- $396
- Updated
- 2024/03/01
- Product number
- R600000
- Product name
- (R)-MOP
- Packaging
- 100mg
- Price
- $220
- Updated
- 2021/12/16
(R)-MOP Chemical Properties,Usage,Production
Uses
(R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate (O701000); an orally active inhibitor of influenza virus neuraminidase and an antiviral drug.
Uses
Takasago Ligands and Complexes for Asymmetric Reactions
Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.
Reactions
1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters.
3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes.
4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins.
5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction.
General Description
R-MOP is a phosphine ligand with a bis-naphthalene backbone.
(R)-MOP Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (R)-MOP manufacturers
- Product
- (R)-MOP 145964-33-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- (R)-(+)-2-Diphenylphosphino-2"-methoxy-1,1"-binaphthyl 145964-33-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- (R)-MOP 145964-33-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1kg,5kg,100kg
- Release date
- 2019-08-08