ChemicalBook > CAS DataBase List > (R)-MOP

(R)-MOP

Product Name
(R)-MOP
CAS No.
145964-33-6
Chemical Name
(R)-MOP
Synonyms
(R)-MOP;R-MOP >=94%;(R)-(+)-MOP;98% (R)-MOP;99% (R)-MOP;(R)-(+)-2-(DiphenyL;phosphino)-2'-methoxy-1,1'-binaphthyL;(S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL;(R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL
CBNumber
CB0180962
Molecular Formula
C33H25OP
Formula Weight
468.52
MOL File
145964-33-6.mol
More
Less

(R)-MOP Property

Melting point:
177-179°C
alpha 
+67° ±2° (c 1, toluene)
Boiling point:
584.1±38.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
almost transparency in Toluene
form 
Powder
color 
white
optical activity
[α]20/D +94°, c = 0.5 in chloroform
Sensitive 
air sensitive
CAS DataBase Reference
145964-33-6(CAS DataBase Reference)
More
Less

Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
2931.90.6000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More
Less

N-Bromosuccinimide Price

TCI Chemical
Product number
D2774
Product name
(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
Purity
>98.0%(GC)
Packaging
1g
Price
$699
Updated
2024/03/01
TCI Chemical
Product number
D2774
Product name
(R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
Purity
>98.0%(GC)
Packaging
100mg
Price
$144
Updated
2024/03/01
Strem Chemicals
Product number
15-1775
Product name
(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
Packaging
100mg
Price
$99
Updated
2024/03/01
Strem Chemicals
Product number
15-1775
Product name
(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
Packaging
500mg
Price
$396
Updated
2024/03/01
TRC
Product number
R600000
Product name
(R)-MOP
Packaging
100mg
Price
$220
Updated
2021/12/16
More
Less

(R)-MOP Chemical Properties,Usage,Production

Uses

(R)-MOP is used as a catalyst in the preparation of chiral tetrahydrobenzofuranone alkylideneboronates and oxindoles. Also used as a catalyst in the total synthesis of Oseltamivir Phosphate (O701000); an orally active inhibitor of influenza virus neuraminidase and an antiviral drug.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.

Reactions

1. Efficient catalyst for the enantoselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
2. Ligand for palladium-catalyzed asymmetric reduction of allyltc esters.
3. Ligand for the rhodium-catalyzed asymmetric aryiation of imines with organostannanes.
4. Ligand for the rhodiunvcatalyzed asymmetrk: addition of aryl- and alkenyiborontc acids to Isatins.
5. Ligand for desymmetrizatlon of malonamides via an enantiosetective intramolecular Buchwatd-Hartwig reaction.

General Description

R-MOP is a phosphine ligand with a bis-naphthalene backbone.

(R)-MOP Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-MOP Suppliers

Americas 1 Belgium 2 China 91 Europe 1 France 1 Germany 2 India 2 Japan 3 Norway 1 Switzerland 1 United Kingdom 1 United States 12 Global 118
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
More
Less

View Lastest Price from (R)-MOP manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-MOP 145964-33-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-08-11
Zhuozhou Wenxi import and Export Co., Ltd
Product
(R)-(+)-2-Diphenylphosphino-2"-methoxy-1,1"-binaphthyl 145964-33-6
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(R)-MOP 145964-33-6
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

145964-33-6, (R)-MOPRelated Search:

MOP (S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl (R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL 8-MOP MOP 4-MOP,5-MOP 1,1'-BINAPHTHYL 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine MOP ANTI-MOP3, HUMAN, 15AA NEAR CT ANTI-MOP3 MOP3, HUMAN, 15AA NEAR CT MOUSE ANTI-8-METHOXYPSORALEN (8MOP) MONOADDUCTS ANTI-MOP3, 22AA NEAR NT MOP4, HUMAN, 15AA INTERNAL DOMAIN ANTI-MOP4, HUMAN, 15AA INTERNAL DOMAIN MOP3, 22AA NEAR NT ANTI-MOP4

  • R-MOP >=94%
  • [(R)-2'-Methoxy[1,1'-binaphthalen]-2-yl]diphenylphosphine,99%e.e.
  • (R)-(+)-2-DIPHENYLPHOSPHINO-2'-METHOXY-1,1'-BINAPHTHYL
  • (S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (R)-(+)-MOP
  • (R)-MOP
  • (S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (R)-(+)-2-(diphenylphosphino)-2’-methoxy-21,1’-binaphthyl(r-mop)
  • (R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP
  • (R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl,99%(R)-MOP
  • (R)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine
  • 98% (R)-MOP
  • [(1R)-2'-METHOXY[1,1'-BINAPHTHALEN]-2-YL]DIPHENYL-PHOSPHINE
  • (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl&gt
  • (R)-(+)-2-(DiphenyL
  • 99% (R)-MOP
  • phosphino)-2'-methoxy-1,1'-binaphthyL
  • Phosphine, [(1R)-2'-methoxy[1,1'-binaphthalen]-2-yl]diphenyl-
  • (R)-(+)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
  • (R)-(2’-Methoxy-[1,1’-binaphthalen]-2-yl)diphenylphosphine
  • (R)-2-(diphenylphosphino)-2'-methoxy-1,1'-binaphthyl (R)-MOP
  • 145964-33-6
  • Chiral Phosphine
  • API intermediates
  • Chiral Reagents