2-Methoxypropene

Product Name: 2-Methoxypropene
CAS No.: 116-11-0
Chemical Name: 2-Methoxypropene
Synonyms: MOP;2-methoxyprop-1-ene;ISOPROPENYL METHYL ETHER;2-Methoxyproene;2-METHYOXYPROPENE;CH2=C(CH3)OCH3;CH3C(OCH3):CH2;2-methoxy-propen;2-METHOXYPROPENE;2-methoxy-1-propen
CBNumber: CB9735606
Molecular Formula: C4H8O
Formula Weight: 72.11
MOL File: 116-11-0.mol

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2-Methoxypropene Property

Melting point:: 25°C
Boiling point:: 34-36 °C (lit.)
Density: 0.753 g/mL at 25 °C (lit.)
vapor pressure: 27.96 psi ( 55 °C)
refractive index: n20/D 1.382(lit.)
Flash point:: −21 °F
storage temp.: 2-8°C
solubility: Chloroform
form: Liquid
color: Clear colorless
PH: 7 (H2O)
Water Solubility: negligible
Sensitive: Light Sensitive
BRN: 1734635
LogP: 1.7 at 21℃ and pH8.1-8.4
CAS DataBase Reference: 116-11-0(CAS DataBase Reference)
NIST Chemistry Reference: 1-Propene, 2-methoxy-(116-11-0)
EPA Substance Registry System: 1-Propene, 2-methoxy- (116-11-0)

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Safety

Hazard Codes: F+,Xn,F
Risk Statements: 12-19-22-11
Safety Statements: 3-16-29-33-7/9-9-18
RIDADR: UN 1993 3/PG 1
WGK Germany: 1
RTECS: UD0800000
F: 8-10
Autoignition Temperature: 374 °F
TSCA: Yes
HazardClass: 3
PackingGroup: I
HS Code: 29091990
Hazardous Substances Data: 116-11-0(Hazardous Substances Data)
Toxicity: rabbit,LD50,skin,> 20mL/kg (20mL/kg),American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H224Extremely flammable liquid and vapour

H302Harmful if swallowed

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 174645
Product name: 2-Methoxypropene
Purity: 97%
Packaging: 50g
Price: $72.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 174645
Product name: 2-Methoxypropene
Purity: 97%
Packaging: 250g
Price: $148
Updated: 2024/03/01

TCI Chemical

Product number: I0303
Product name: 2-Methoxypropene
Purity: >95.0%(GC)
Packaging: 25mL
Price: $78
Updated: 2024/03/01

TCI Chemical

Product number: I0303
Product name: 2-Methoxypropene
Purity: >95.0%(GC)
Packaging: 100mL
Price: $204
Updated: 2024/03/01

Alfa Aesar

Product number: B24083
Product name: 2-Methoxypropene, 95%, stab. with ca 0.5% potassium carbonate
Packaging: 50g
Price: $45.1
Updated: 2024/03/01

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2-Methoxypropene Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

2-Methoxypropene is used in the synthesis of Macrolactin A, a 24-member macrolide typically employed as an antibiotic. Also used in the synthesis of phenylalanine derivatives used as α4β1 and α4β7 receptor antagonists in the treatment of allergic asthma.

Preparation

2-Methoxypropene is prepared in high yield from Succinic Anhydride, 2,2-Dimethoxypropane, benzoic acid, and Pyridine.

Reactivity Profile

2-Methoxypropene is an electron-rich alkene used in the monoprotection of aliphatic, allylic, and propargylic alcohols, often followed by Claisen or other rearrangements; protection of peroxides, cyanohydrins, α-hydroxy ketones, and phenols; condensation with amines; protection of 1,2- and 1,3-diols, sometimes followed by Prins rearrangements; protection of 1,2-dithiols and α-hydroxy carbamates; participant in pericyclic reactions; formation of 2-methoxyallyl halides and substituted furans.

Toxics Screening Level

The initial threshold screening level (ITSL) for 2-Methoxy-1-propene is 6 μg/m3 based on an annual averaging time.

Precautions

flammable liquid; light-sensitive; should be refrigerated.

2-Methoxypropene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methoxypropene Suppliers

Americas 1 Belgium 2 Canada 1 CHINA 240 Europe 5 Germany 8 India 20 Japan 4 Slovakia 1 South Korea 1 Switzerland 3 Ukraine 1 United Kingdom 13 United States 29 Global 329

Wuhan xinyangruihe Chemical Technology Co., Ltd.

Tel: 18120580375 18120580375
Fax: 027-83850375
Email: 669797270@qq.com
Country: China
ProdList: 4985
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9371
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44731
Advantage: 61

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 2988
Advantage: 65

Wuhan Chemwish Technology Co., Ltd

Tel: 86-027-67849912
Fax: 86-027-87531808
Email: sales@chemwish.com
Country: China
ProdList: 35896
Advantage: 56

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

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View Lastest Price from 2-Methoxypropene manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 2-Methoxypropene 116-11-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-09-12

Hebei Weibang Biotechnology Co., Ltd

Product: 2-Methoxypropene 116-11-0
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-20

Hebei Chuanghai Biotechnology Co,.LTD

Product: 2-Methoxypropene 116-11-0
Price: US $10.70/kg
Min. Order: 10kg
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

116-11-0, 2-MethoxypropeneRelated Search:

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Methyl isopropenyl ether

2-METHOXYPROPENE

2-METHOXY-1-PROPENE

MOP

ISOPROPENYL METHYL ETHER

1-Propene,2-methoxy-

2-methoxy-1-propen

2-methoxy-prop-1-ene

2-methoxyprop-1-ene

2-methoxy-propen

CH2=C(CH3)OCH3

Ether, isopropenyl methyl

ether,isopropenylmethyl

2-METHOXYPROPENE, STAB.

2-METHYOXYPROPENE

2-Methoxypropene, stabilized, 98%

2-METHOXYPROPENE , STABILIZED WITH CA 0.5% POTASSIUM CARBONATE

2-METHOXYPROPENE, 99.5+%

2-METHOXYPROPENE:ISOPROPENYL METHYL ETHER 99%

2-Methoxypropene, 98%, stab. with ca 0.5% potassium carbonate

2-Methoxypropene, 99%, stab. with ca 0.5% potassium carbonate

Methyl 1-methylvinyl ether

Methyl 1-propene-2-yl ether

Methyl α-methylvinyl ether

2-Methoxypropene,97%,stabilized

2-Methoxyproene

CH3C(OCH3):CH2

2-Methoxypropene, stabilized, 97% 250ML

2-Methoxypropene, 95%, stab. with ca 0.5% potassiuM carbonate

2-Methoxypropene, 95%, stabilized

Isopropenyl methyl ethe

2-Methoxypropene, 98%, stabilized

2-Methoxypropene, Stabilized with PotassiuM Carbonate

2-Methoxy-1-propene for synthesis

2-Methoxypropene, stabilized with &ap:0.5% potassium carbonate

2-Methoxypropene&gt

TIANFUCHEM--High purity 116-11-0 2-Methoxypropene

2-METHOXYPROPENE (STABILIZED) Extra Pure

Aminocaproic acid impurity 4 (methyl oleyl phthalate)

116-11-0

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