Triphenylsilyl chloride
?Acute toxicity- Product Name
- Triphenylsilyl chloride
- CAS No.
- 76-86-8
- Chemical Name
- Triphenylsilyl chloride
- Synonyms
- Chlorotriphenylsilane;P3;TRIPHENYLCHLOROSILANE;TPCS;TRIPHENLCHLOROSILANE;chlorotriphenyl-silan;Triphenylchlorsoilane;TRIPHENYLSILYL CHLORIDE;silane,chlorotriphenyl-;triphenylchlorosilicane
- CBNumber
- CB0191735
- Molecular Formula
- C18H15ClSi
- Formula Weight
- 294.85
- MOL File
- 76-86-8.mol
Triphenylsilyl chloride Property
- Melting point:
- 91-94 °C(lit.)
- Boiling point:
- 378 °C
- Density
- 1.14
- Flash point:
- >200°C
- storage temp.
- Refrigerator
- solubility
- acetone: 0.1 g/mL, clear
- form
- crystal
- color
- white
- Specific Gravity
- 1.16
- Water Solubility
- Reacts with water.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 1820487
- InChIKey
- MNKYQPOFRKPUAE-UHFFFAOYSA-N
- CAS DataBase Reference
- 76-86-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Triphenylchlorosilane(76-86-8)
- EPA Substance Registry System
- Silane, chlorotriphenyl- (76-86-8)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-37
- Safety Statements
- 26-36/37/39-45-24/25
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 1
- RTECS
- VV2720000
- F
- 10-21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29310095
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 114162
- Product name
- Chlorotriphenylsilane
- Purity
- 96%
- Packaging
- 5g
- Price
- $47.6
- Updated
- 2024/03/01
- Product number
- 114162
- Product name
- Chlorotriphenylsilane
- Purity
- 96%
- Packaging
- 25g
- Price
- $108
- Updated
- 2024/03/01
- Product number
- T0939
- Product name
- Triphenylchlorosilane
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $25
- Updated
- 2024/03/01
- Product number
- T0939
- Product name
- Triphenylchlorosilane
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $92
- Updated
- 2024/03/01
- Product number
- A13678
- Product name
- Chlorotriphenylsilane, 96%
- Packaging
- 5g
- Price
- $22.65
- Updated
- 2024/03/01
Triphenylsilyl chloride Chemical Properties,Usage,Production
?Acute toxicity
IV- mouse LD50: 56 mg/kg
Description
Triphenylsilyl chloride is a white to off-white crystal or powder with acrid ordor of hydrogen chloride, used for synthesis of pharmaceutical intermediates.
Physical properties
mp 92–94°C; bp 240–243°C/35 mmHg.
Uses
Chlorotriphenylsilane is used as a silylating agent. It is also used as a pharmaceutical intermediate.
Uses
A wide variety of Grignard reagents and organolithium complexes
participate in reactions with Ph3SiCl to afford organosilanes.
Thus the reaction of allylmagnesium chloride with Ph3SiCl gives the allylsilane in high yield (eq 3).However, when hydrosilyl
Grignard reagents are employed, reduction to the silane
occurs (eq 4).Azaallyl anion6 and diazolithium salts can each
be silylated to give the anticipated silane adducts (eqs 5 and 6).
Similarly, arylsilanes8 and alkynylsilanes are produced upon
silylation of the appropriate metalated13 carbanions with Ph3SiCl
(eqs 7–11).
Purification Methods
Likely impurities are tetraphenylsilane, small amounts of hexaphenyldisiloxane and traces of triphenylsilanol. Purify it by distillation at 2mm, then crystallise it from EtOH-free CHCl3, and from pet ether (b 30-60o) or hexane by cooling in a Dry-ice/acetone bath. [Allen & Modena J Chem Soc 3671 1957, Curran et al. J Am Chem Soc 72 4471 1950, Speier & Zimmerman J Am Chem Soc 77 6395 1955, Thomas & Rochow J Am Chem Soc 79 1843 1957, Beilstein 16 IV 1484.]
Triphenylsilyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Triphenylsilyl chloride manufacturers
- Product
- Triphenylsilyl chloride 76-86-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-06-30
- Product
- Triphenylsilyl chloride 76-86-8
- Price
- US $9.90/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2021-09-24
- Product
- Triphenylsilyl chloride 76-86-8
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11