METHYL 5-CHLORO-2-IODOBENZOATE
- Product Name
- METHYL 5-CHLORO-2-IODOBENZOATE
- CAS No.
- 289039-82-3
- Chemical Name
- METHYL 5-CHLORO-2-IODOBENZOATE
- Synonyms
- METHYL 5-CHLORO-2-IODOBENZOATE;5-chloro-2-iodo-Benzoic acid Methyl ester;Benzoic acid, 5-chloro-2-iodo-, methyl ester;5-chloro-2-iodo-Benzoic acid methyl ester (9CI ACI);Benzoic acid, 5-chloro-2-iodo-, methyl ester (9CI, ACI)
- CBNumber
- CB0245065
- Molecular Formula
- C8H6ClIO2
- Formula Weight
- 296.49
- MOL File
- 289039-82-3.mol
METHYL 5-CHLORO-2-IODOBENZOATE Property
- Boiling point:
- 295.6±20.0 °C(Predicted)
- Density
- 1.837±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- Appearance
- Light yellow to yellow Solid
- InChI
- InChI=1S/C8H6ClIO2/c1-12-8(11)6-4-5(9)2-3-7(6)10/h2-4H,1H3
- InChIKey
- LNCNRPALSKTJBG-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC(Cl)=CC=C1I
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H320Causes eye irritation
H336May cause drowsiness or dizziness
H351Suspected of causing cancer
H410Very toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
P391Collect spillage. Hazardous to the aquatic environment
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B495078
- Product name
- Methyl5-Chloro-2-iodobenzoate
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- 098313
- Product name
- Methyl 5-chloro-2-iodobenzoate
- Packaging
- 1g
- Price
- $65
- Updated
- 2021/12/16
- Product number
- CS-0030377
- Product name
- 5-Chloro-2-iodobenzoicacidmethylester
- Packaging
- 1g
- Price
- $87
- Updated
- 2021/12/16
- Product number
- 098313
- Product name
- Methyl 5-chloro-2-iodobenzoate
- Packaging
- 25g
- Price
- $995
- Updated
- 2021/12/16
- Product number
- A123880
- Product name
- Methyl5-chloro-2-iodobenzoate
- Purity
- 95%
- Packaging
- 100mg
- Price
- $6
- Updated
- 2021/12/16
METHYL 5-CHLORO-2-IODOBENZOATE Chemical Properties,Usage,Production
Synthesis
67-56-1
13421-00-6
289039-82-3
General procedure for the synthesis of methyl 5-chloro-2-iodobenzoate from methanol and 5-chloro-2-iodobenzoic acid: a mixture of 5-chloro-2-iodobenzoic acid (3.0 g, 10.62 mmol), dichlorosulfoxide (12 mL), and N,N-dimethylformamide (0.6 mL) was gently heated with a heat gun until a homogeneous solution was formed (about 15 minutes). Subsequently, the reaction solution was continued to be stirred at 23 °C for 30 min, after which the solvent was removed by concentration under reduced pressure. Methanol (24 mL) was added to the crude product and stirred at 23 °C for 30 min. After the reaction was completed, the reaction solution was again concentrated under reduced pressure. The crude product was purified by rapid chromatography on a Biotage silica gel column with a gradient of cyclohexane to cyclohexane:ethyl acetate (85:15) as eluent to give methyl 5-chloro-2-iodobenzoate (3.02 g, 10.20 mmol, 96% yield).UPLC-MS analysis showed a retention time of 1.17 min and a molecular ion peak m/z 296.6 [M + H]+ , analyzed by method 12.
References
[1] Patent: WO2015/91685, 2015, A1. Location in patent: Page/Page column 69
[2] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 10, p. 2823 - 2827
[3] Angewandte Chemie - International Edition, 2013, vol. 52, # 28, p. 7177 - 7180
METHYL 5-CHLORO-2-IODOBENZOATE Preparation Products And Raw materials
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View Lastest Price from METHYL 5-CHLORO-2-IODOBENZOATE manufacturers
- Product
- Benzoic acid, 5-chloro-2-iodo-, Methyl ester 289039-82-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27