TriMethyl(broModifluoroMethyl)silane
- Product Name
- TriMethyl(broModifluoroMethyl)silane
- CAS No.
- 115262-01-6
- Chemical Name
- TriMethyl(broModifluoroMethyl)silane
- Synonyms
- (BroModifluoroMethyl)triMethylsilane;(Bromodifluoromethyl);Difluorobromomethylsilane;TriMethyl(broModifluoroMethyl)silane;Bromodifluoro(trimethylsilyl)methane;Silane, (bromodifluoromethyl)trimethyl-;Trimethyl(bromodifluoromethyl)silane 97%;(Bromodifluoromethyl)trimethylsilane 98%;(Bromodifluoromethyl)trimethylsilane >(Bromodifluoromethyl)trimethylsilane, 98+%
- CBNumber
- CB02611493
- Molecular Formula
- C4H9BrF2Si
- Formula Weight
- 203.1
- MOL File
- 115262-01-6.mol
TriMethyl(broModifluoroMethyl)silane Property
- Boiling point:
- 108°C(lit.)
- Density
- 1.306
- refractive index
- n/D1.407
- Flash point:
- 46℃
- storage temp.
- -20°C
- form
- liquid
- color
- clear
- InChIKey
- WDZVWBWAUSUTTO-UHFFFAOYSA-N
- CAS DataBase Reference
- 115262-01-6
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 808601
- Product name
- (Bromodifluoromethyl)
- Purity
- 98%
- Packaging
- 1g
- Price
- $118
- Updated
- 2023/01/07
- Product number
- B4325
- Product name
- (Bromodifluoromethyl)trimethylsilane
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $93
- Updated
- 2024/03/01
- Product number
- B4325
- Product name
- (Bromodifluoromethyl)trimethylsilane
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $281
- Updated
- 2024/03/01
- Product number
- T895825
- Product name
- Trimethyl(bromodifluoromethyl)silane
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- FB60402
- Product name
- (Bromodifluoromethyl)trimethylsilane
- Packaging
- 500mg
- Price
- $60
- Updated
- 2021/12/16
TriMethyl(broModifluoroMethyl)silane Chemical Properties,Usage,Production
Uses
Novel difluorocarbene source for the efficient difluoromethylenation of alkenes/alkynes and difluoromethylation of O-, S-, and N-nucleophiles.
Uses
Trimethyl(bromodifluoromethyl)silane can be used as neuroactive steroids.
Uses
As reported by Hu and co-workers, (Bromodifluoromethyl)trimethylsilane is a highly useful reagent for the formation of difluoromethene-containing 3-membered rings and can also difluoromethylate heteroatoms with the assistance of alkaline bases, most effectively KOH.
Reactions
(1) Difluoromethylenation of TMSCN.
Ref. J. Org. Chem. 2012, 77, 5850?5855.
(2) Difluoromethylenation of benzyl and alkylzinc halides.
Ref. Org. Lett. 2013, 15, 917 – 919.
(3) Fluorination aminocarbonylation of aldehydes
Ref. Angew. Chem. Int. Ed. 2022, e202115467
General Description
(Bromodifluoromethyl)trimethylsilane (TMSCF2Br) is commonly used as a source to generate dilfluorocarbene. TMSCF3 (Ruppert–Prakash reagent) and BBr3 undergoes fast halogen–exchange reaction to form MSCF2Br.
References
[1]Angewandte Chemie International Edition.DOI :10.1002/anie.202283811
[2]The Journal of Organic Chemistry.DOI :10.1021/acs.orglett.2c02899
TriMethyl(broModifluoroMethyl)silane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TriMethyl(broModifluoroMethyl)silane manufacturers
- Product
- TriMethyl(broModifluoroMethyl)silane 115262-01-6
- Price
- US $0.10-0.10/kg
- Min. Order
- 0.004999999888241291kg
- Purity
- 99.99%
- Supply Ability
- 20 tons
- Release date
- 2024-04-15
- Product
- TriMethyl(broModifluoroMethyl)silane 115262-01-6
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
- Product
- (Bromodifluoromethyl)trimethylsilane 115262-01-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10